370391

Integration of CO2 capturing from flue gases using Aqueous Ammonia for Low Emissions Urea Production

Article

Last updated: 15 Feb 2025

Subjects

-

Tags

Environmental chemistry

Abstract

Carbon Capture and Utilization is one the potential solution to mitigate global warming. In this study, aqueous ammonia is used for capturing CO2 from flue gases, the produced slurry is then utilized for urea production. In this work, modification is conducted to the original solid controlled formation chilled ammonia process. During this, ammonium carbonate slurry is produced, which can play a crucial part as intermediate element in urea synthesis. Process stream integration and waste energy utilization are considered in many points, in addition to, urea revamp to accommodate this modification.



The proposed modification is simulated in Aspen Plus using extended thermodynamics model. Due to this modification and process integration, the regeneration section and effluent treatment section were completely removed which greatly decreased energy consumption. It is found that, energy consumption in the solid controlled formation process decreased by 23.4%. Moreover, through the proposed energy integration with the urea production plant, a zero-energy consumption is reached together with an increase in urea production by 8 t/hr. This also has an environmental impact as the amount of associated CO2 emissions decreased by 6% which affected the carbon footprint of the plant. Our work is in agreement with the United Nation Sustainable Development Goals; goals number 2, 7 and 13. Utilizing carbon dioxide emissions initiated a transformative shift in industrial practices in alignment with sustainability requirements.

DOI

10.21608/ejchem.2024.291337.9749

Keywords

Carbon Capture and Utilization (CCU), Aqueous Ammonia Process, Post-combustion Capture, Urea Production, Carbon footprint, Sustainable Urea

Authors

First Name

Rehab

Last Name

El-Maghraby

MiddleName

M.

Affiliation

Petroleum Refinery and Petrochemical Engineering Department, Faculty of Petroleum and Mining Engineering, Suez University

Email

rehab.elmaghraby@suezuniv.edu.eg

City

-

Orcid

-

First Name

Mohamed

Last Name

Behairy

MiddleName

-

Affiliation

Misr Fertlizers Production Company (MOPCO), Dameitta, Egypt

Email

mohamed.behaairy@gmail.com

City

-

Orcid

-

First Name

Mohammed

Last Name

Fathy

MiddleName

-

Affiliation

Egyptian Refinery Company (ERC), Cairo, Egypt

Email

mfathy@ercegypt.com

City

-

Orcid

-

Volume

68

Article Issue

2

Related Issue

53637

Issue Date

2025-02-01

Receive Date

2024-05-21

Publish Date

2025-02-01

Page Start

361

Page End

370

Print ISSN

0449-2285

Online ISSN

2357-0245

Link

https://ejchem.journals.ekb.eg/article_370391.html

Detail API

http://journals.ekb.eg?_action=service&article_code=370391

Order

370,391

Type

Original Article

Type Code

297

Publication Type

Journal

Publication Title

Egyptian Journal of Chemistry

Publication Link

https://ejchem.journals.ekb.eg/

MainTitle

Integration of CO2 capturing from flue gases using Aqueous Ammonia for Low Emissions Urea Production

Details

Type

Article

Created At

08 Feb 2025