Beta
361810

The comparison effects of quinoa stalks activated carbon on adsorption of cadmium and lead polluted soils

Article

Last updated: 01 Jan 2025

Subjects

-

Tags

Environmental chemistry

Abstract

The study was performed to investigate the effect of activated carbons (ACs) in dose 2% w/w produced from agricultural wastes as Quinoa stalks (Q-AC), rice straws (R-AC) and corn stalks (C-AC) on different soils (clay and sandy loam) polluted by heavy metals (HMs) 100 mg. Kg-1 cadmium (Cd100), 600 mg. Kg-1 Lead (Pb 600) or mixture of both elements (Cd100/Pb 600). The physical and chemical properties of ACs were assessed accordingly. The total carbon % values were higher in Q-AC (49.82%) than R-AC and C-AC, respectively. The surface area (BET) of AC samples were ranged from 489.314 to 1084.120 m2. g-1. The total pores volume (Vtotal) was increased in Q-AC (1.234 m2. g-1). SEM images proved high porosity of the Q-AC compared to R-AC or C-AC. The Fourier Transform Infrared spectroscopy (FTIR) analysis indicated the most porous activated carbon efficiency for adsorbing as carbonyl (C=O), carboxlic (C-O) and hydroxyl (–OH) groups in Q-AC played an important role in the adsorption process. Furthermore, the adsorption isotherm was examined the maximum adsorption capacity for Cd, Pb or mixture. Results showed that the highest adsorption capacity (Qm) of Q-AC followed by R-AC and C-AC, respectively for individual Cd, Pb or mixture. In conclusion, the most effective AC was Q-AC followed by R-AC then R-AC in maximum adsorption capacity for Cd, Pb or mixture to remediate polluted soils according to their physical and chemical characteristics. The lignocellulose-rich agro-industrial waste produced effective activated carbons depends upon the total carbon content, surface area, pore size and volume, surface functionalities that offer economical and easy availability way to remediate the heavy metals polluted soils.

DOI

10.21608/ejchem.2024.275802.9433

Keywords

soils remediation, cadmium, Lead, Activated carbon, agricultural wastes

Authors

First Name

Hend

Last Name

Nour

MiddleName

M.

Affiliation

RCFF, Agricultural Research Center - Giza- Egypt.

Email

hendnour443@gmail.com

City

Giza

Orcid

-

First Name

Hassan

Last Name

Khater

MiddleName

A.

Affiliation

Soil Sciences Department, Faculty of Agriculture, Cairo University, Giza, Egypt.

Email

hakhater2000@agr.cu.edu.eg

City

Giza

Orcid

-

First Name

Asmaa

Last Name

Salem

MiddleName

Ahmed

Affiliation

Regional Center for Food and Feed (RCFF), Agriculture Research Center, Giza, Egypt,

Email

namesaaa2013@gmail.com

City

-

Orcid

https://orcid.org/00

First Name

Noha

Last Name

Abdelkader

MiddleName

H.

Affiliation

Soil Sciences Department, Faculty of Agriculture, Cairo University, Giza, Egypt.

Email

noha.abdulkader@agr.cu.edu.eg

City

Giza

Orcid

-

Volume

67

Article Issue

10

Related Issue

49535

Issue Date

2024-10-01

Receive Date

2024-03-12

Publish Date

2024-10-01

Page Start

475

Page End

486

Print ISSN

0449-2285

Online ISSN

2357-0245

Link

https://ejchem.journals.ekb.eg/article_361810.html

Detail API

https://ejchem.journals.ekb.eg/service?article_code=361810

Order

361,810

Type

Original Article

Type Code

297

Publication Type

Journal

Publication Title

Egyptian Journal of Chemistry

Publication Link

https://ejchem.journals.ekb.eg/

MainTitle

The comparison effects of quinoa stalks activated carbon on adsorption of cadmium and lead polluted soils

Details

Type

Article

Created At

30 Dec 2024