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340983

A Highly Selective Potentiometric Sensor for Detection of Zn(II) in Petroleum Water Samples Using Carbon Paste Electrode Based on Molecular Imprinted Polymer

Article

Last updated: 01 Jan 2025

Subjects

-

Tags

Environmental chemistry

Abstract

For the purpose of determining the presence of zinc(II) in petroleum water samples, a molecular imprinted polymer (MIP) based modified carbon paste potentiometric method was described. Methacrylic acid monomers and ethylene glycol dimethacrylate were used in the polymerization process to create the MIP. The generated imprinted polymer was evaluated using flame atomic absorption spectrometry, Fourier transform infrared spectroscopy (FT-IR), and proton nuclear magnetic resonance (1H-NMR). It was then used as a sorbent for selective magnetic solid phase extraction of zinc(II) ion. Using MIP as a suitable neutral carrier, a label modified carbon paste electrode (MCPEs) that is highly selective to Zn(II) ions was created. For MCPEs (Sensors I and II), they demonstrated a linear concentration range from 1.0x10-7 to 1.0x10-1 mol L-1 with Nernstian slopes of 28.43±0.63 and 29.27±0.48 mV decade-1, respectively. The suggested electrodes were successful applied in determining the Zn(II) ion concentrations in water samples. The outcomes were comparable to those from atomic absorption spectroscopy (AAS) in actual spiked water samples.

DOI

10.21608/ejchem.2024.247470.8869

Keywords

Chemically modified carbon paste sensor, Zn(II) determination, Imprinted molecular polymer, Potentiometric sensor, Petroleum water sample

Authors

First Name

Yassmin

Last Name

Emad

MiddleName

-

Affiliation

Chemistry Department, Faculty of Science, Helwan University

Email

yasmen.emad.highed@science.edu.eg

City

Cairo

Orcid

-

First Name

Tamer

Last Name

Ali

MiddleName

Awad

Affiliation

Egyptian Petroleum Research Institute (EPRI), 11727, Cairo, Egypt.

Email

dr_tamerawad@hotmail.com

City

Nasr City

Orcid

0000-0002-5897-0005

First Name

Gehad

Last Name

Mohamed

MiddleName

Genidy

Affiliation

Chemistry Department, Faculty of Science, Cairo University, 12613 Giza Egypt

Email

ggenidymohamed@gmail.com

City

Cairo

Orcid

0000-0002-1525-5271

First Name

Madiha

Last Name

Hassan

MiddleName

-

Affiliation

Chemistry, Faculty of Science, Helwan University

Email

drmadihahasn@yahoo.com

City

Cairo

Orcid

0000-0003-1825-5119

First Name

Abdel El-Fatah

Last Name

Bastawy

MiddleName

-

Affiliation

Chemistry Department, Faculty of Science, Helwan University

Email

abfarag82@yahoo.com

City

Cairo

Orcid

0009-0006-1799-578X

Volume

67

Article Issue

9

Related Issue

48208

Issue Date

2024-09-01

Receive Date

2023-11-13

Publish Date

2024-09-01

Page Start

507

Page End

521

Print ISSN

0449-2285

Online ISSN

2357-0245

Link

https://ejchem.journals.ekb.eg/article_340983.html

Detail API

https://ejchem.journals.ekb.eg/service?article_code=340983

Order

340,983

Type

Original Article

Type Code

297

Publication Type

Journal

Publication Title

Egyptian Journal of Chemistry

Publication Link

https://ejchem.journals.ekb.eg/

MainTitle

A Highly Selective Potentiometric Sensor for Detection of Zn(II) in Petroleum Water Samples Using Carbon Paste Electrode Based on Molecular Imprinted Polymer

Details

Type

Article

Created At

30 Dec 2024