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226350

ADSORPTION AND RELEASE OF CADMIUM IN SOME SOILS OF EGYPT.

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Last updated: 22 Jan 2023

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Abstract

Cadmium adsorption by and release from five soils representing the soils of Egypt; alluvial, calcareous, and sandy soils, were studied. Soil samples collected from the top 20 cm were equilibrated with CdCl2 solutions containing up to 800 µg Cd/ml. The absorbed Cd was subsequently extracted with 1M ammonium acetate (exchangeable-Cd) and 0.125 M copper (II) acetate (complexed-Cd). The adsorption of Cd by soils was highly fitted to Langmuir and Freundlich isotherms with (r2) values ranging from 0.962 to 0.993 with the former and from 0.945 to 0.987 with the later. The Cd adsorption maxima calculated from Langmuir isotherm ranged  from 1.885 to 8.830 mg/g soil (3.35 to 15.71 meq/100g soil) and was significantly correlated with clay + silt content, cation exchange capacity (CEC), and organic matter content (OM). The corresponding values calculated from Freundlich isotherm ranged from 0.18 to 0.88 mg Cd/g soil and were not correlated with any of the studied soil properties.  About 80 to 95 percent of adsorbed Cd was retained by cation exchange and complexing sites. Cation exchange sites assumed to play more important role in adsorbing Cd than complexing sites with increasing adsorption, except in calcareous soil, which exhibited a comparable importance of the two kinds of sites. Such results are important to understand the fate of Cd added to the soil through applications of contaminated sludges and wastes and to develop useful environmental guidelines for its potential toxic hazards. 

DOI

10.21608/jssae.2005.226350

Keywords

cadmium, Adsorption, desorption, Heavy metals, Soils of Egypt

Authors

First Name

M. G. A.

Last Name

Rehan

MiddleName

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Affiliation

Soils, Water and Environment. Res. Institute, ARC, Giza, Egypt.

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Volume

30

Article Issue

3

Related Issue

32476

Issue Date

2005-03-01

Receive Date

2005-03-22

Publish Date

2005-03-01

Page Start

1,725

Page End

1,738

Print ISSN

2090-3685

Online ISSN

2090-3766

Link

https://jssae.journals.ekb.eg/article_226350.html

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https://jssae.journals.ekb.eg/service?article_code=226350

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2

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Original Article

Type Code

889

Publication Type

Journal

Publication Title

Journal of Soil Sciences and Agricultural Engineering

Publication Link

https://jssae.journals.ekb.eg/

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Article

Created At

22 Jan 2023