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200477

Eco-Friendly Roselle (Hibiscus Sabdariffa) Leaf Extract as Naturally Corrosion Inhibitor for Cu-Zn Alloy in 1M HNO3

Article

Last updated: 01 Jan 2025

Subjects

-

Tags

Electrochemistry

Abstract

The eco-friendly compounds especially plant extracts have emerged as green corrosion inhibitors for metals and alloys. The inhibiting impact of Roselle extract on Cu-Zn alloy in 1M HNO3 solution was studied by weight loss, electrochemical impedance spectroscopy (EIS), and potentiodynamic polarization (PDP). It was found that Roselle extract acts as a good mixed-type corrosion inhibitor for Cu-Zn alloy in acid solution. The corrosion rate decreases with increasing the extract concentration and increases with raising the temperature. The formation of a protecting film on the Cu-Zn alloy surface with the presence of Roselle extract was confirmed by scanning electron microscopy (SEM), and energy-dispersive X-ray (EDX). The high inhibition efficiency of 94.89 % was recorded for 80% extract solution. There are good agreements between the results from all techniques.

DOI

10.21608/ejchem.2021.92917.4392

Keywords

Cu-Zn alloy, Nitric acid, Corrosion inhibition, Roselle (Hibiscus Sabdariffa) extract

Authors

First Name

Seham

Last Name

Shahen

MiddleName

-

Affiliation

Department of Chemistry, Faculty of Science (Girls), Al-Azhar University, P.O. Box: 11754, Yousef Abbas Str., Nasr City, Cairo, Egypt

Email

seham@azhar.edu.eg

City

Giza

Orcid

0000-0001-1751-3143

First Name

Amal

Last Name

Abdel-karim

MiddleName

M

Affiliation

Physical Chemistry department, NRC, Dokki, Giza, Egypt.

Email

amalabdelkarim720@yahoo.com

City

Giza

Orcid

0000-0001-9210-084x

First Name

Ghalia

Last Name

Gaber

MiddleName

A.

Affiliation

Department of chemistry, Faculty of Science(Girls), Al-Azhar University.P.O.Box:11754, Yousef Abbas Str.,Nasr city,Cairo, Egypt

Email

ghaliaasaid@yahoo.com

City

-

Orcid

-

Volume

65

Article Issue

4

Related Issue

29683

Issue Date

2022-04-01

Receive Date

2021-08-27

Publish Date

2022-04-01

Page Start

351

Page End

361

Print ISSN

0449-2285

Online ISSN

2357-0245

Link

https://ejchem.journals.ekb.eg/article_200477.html

Detail API

https://ejchem.journals.ekb.eg/service?article_code=200477

Order

34

Type

Original Article

Type Code

297

Publication Type

Journal

Publication Title

Egyptian Journal of Chemistry

Publication Link

https://ejchem.journals.ekb.eg/

MainTitle

Eco-Friendly Roselle (Hibiscus Sabdariffa) Leaf Extract as Naturally Corrosion Inhibitor for Cu-Zn Alloy in 1M HNO3

Details

Type

Article

Created At

22 Jan 2023