188618

Green Synthesis of copper Nanoparticles: Synthesis, Characterization and their application: About Future

Article

Last updated: 01 Jan 2025

Subjects

-

Tags

Physical chemistry

Abstract

In the present study copper oxide nanoparticles (CuNPs) were synthesized via simple and eco-friendly green route using black tea extract . Characterization of synthesized nanoparticles (NPs) was undertaken. The characteristic absorption peak of CuNPs was in range (352-355) nm in UV–Vis spectrum. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) studies revealed the morphological and structural character of green NPs. The particle size was 25-50 nm. Energy dispersive spectroscopy (EDX) showed high intense metallic peak of copper (Cu), oxygen (O), carbon (C) and low intense peaks of phosphorus (P) , calcium (Ca) , sulfur (S), potassium (K) elements due to the capping action of biomolecules of plant extract in CuNPs formation. The X-ray diffraction (XRD) pattern showed distinctive peaks corresponding to (200), (220) and (311) planes revealing the high crystalline nature of synthesized CuNPs . The dyeing behavior of green CuNPs treated fabric with Acid Black 172 (AB 172) has been studied and the build up of dye, measured as exhaustion percentage (E%). Dye adsorption rate constants according to pseudo-first order, pseudo-second order, and intra-particle diffusion kinetic models were calculated. Moreover, the dye adsorption equilibrium data were fitted well to the Freundlich isotherm rather than Langmuir isotherm. The overall adsorption process follow pseudo-second order kinetics, Intraparticle diffusion and Elovich model. The CuNPs treatment produces a nylon fabric with advanced color fastness and antibacterial properties enabling them to improve human health care and reducing temperature, the environmental impacts, fabric damage, amount of dyestuff used and saving energy of conventional dyeing of nylon fabrics. This review focuses on green synthesis of CuNPs using environmentally benign reagents in minimal time paves the way for future studies on CuNPs toxicity without risking interference from potentially toxic reagents and capping agents. The use of this technique to treat nylon fabric may lead to new coloration technique and other functional improvement.

DOI

10.21608/ejchem.2021.87059.4209

Keywords

Keywords: green synthesis, Copper nanoparticles, nylon fabric, acid black 172, Antimicrobial, dyeing process

Authors

First Name

rania

Last Name

saleh

MiddleName

-

Affiliation

Benghazi university , Benghazi- Libya

Email

raniasaleh58@yahoo.com

City

-

Orcid

-

First Name

alshimaa

Last Name

gomaa

MiddleName

hassen

Affiliation

chemistry , science, al-azhar university (girls), nasr city, cairo, egypt

Email

alshimaa@azhar.edu.eg

City

cairo

Orcid

0000-0001-9313-2608

First Name

Asrar

Last Name

Elsayed

MiddleName

Gomaa

Affiliation

Faculty of Science – Al-Azhar University (Girls)

Email

asrargoma@yahoo.com

City

-

Orcid

-

First Name

ahmed

Last Name

daher

MiddleName

-

Affiliation

Nuclear Material Authority, Nasr City.

Email

doctor_daher@yahoo.com

City

-

Orcid

-

Volume

65

Article Issue

2

Related Issue

28751

Issue Date

2022-02-01

Receive Date

2021-07-21

Publish Date

2022-02-01

Page Start

357

Page End

368

Print ISSN

0449-2285

Online ISSN

2357-0245

Link

https://ejchem.journals.ekb.eg/article_188618.html

Detail API

https://ejchem.journals.ekb.eg/service?article_code=188618

Order

39

Type

Original Article

Type Code

297

Publication Type

Journal

Publication Title

Egyptian Journal of Chemistry

Publication Link

https://ejchem.journals.ekb.eg/

MainTitle

Green Synthesis of copper Nanoparticles: Synthesis, Characterization and their application: About Future

Details

Type

Article

Created At

22 Jan 2023