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412089

Adsorption and inhibitive impact of 5-(2-ethoxybenzylidene) 1,3-dimethylbarbituric acid on carbon steel corrosion in acid solution

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Last updated: 25 Feb 2025

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Abstract

The inhibiting impact of ecofriendly 5-(2-ethoxybenzylidene) 1,3-dimethylbarbituric acid (5-EBMB) in 1 M HCl on the corrosion of C-steel has been examined via weight loss (WL) method, potentiodynamic polarization (PP), electrochemical impedance spectroscopy (EIS), electrochemical frequency modulation (EFM) techniques. The attained outcomes exhibit that the investigated compound is excellent inhibitor and its inhibition efficiency (%IE) rises by rising concentration and temperature. The adsorption of the investigated derivative on the surface of C-steel follows Langmuir isotherm. The adsorption process of the investigated compound is spontaneous and considered as chemisorption type. PP curves revealed that the studied derivative is mixed-type inhibitor. Moreover, EIS results confirmed the adsorption of the investigated compound on C-steel surface via increasing on charge transfer resistance (Rct) and lowering in capacitance of double layer (Cdl). The IE% of the investigated derivative reached to 79.9% at concentration 21×10-6 M according to WL method. All tested methods gave good agreement.

DOI

10.21608/mjcc.2022.412089

Keywords

carbon steel, Adsorption, inhibitive, Corrosion

Volume

55

Article Issue

1

Related Issue

53849

Issue Date

2022-02-01

Receive Date

2025-02-17

Publish Date

2022-02-01

Page Start

32

Page End

41

Print ISSN

1687-5060

Online ISSN

2974-4938

Link

https://micc.journals.ekb.eg/article_412089.html

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http://journals.ekb.eg?_action=service&article_code=412089

Order

412,089

Type

Original Article

Type Code

3,440

Publication Type

Journal

Publication Title

Mansoura Journal of Chemistry

Publication Link

https://micc.journals.ekb.eg/

MainTitle

Adsorption and inhibitive impact of 5-(2-ethoxybenzylidene) 1,3-dimethylbarbituric acid on carbon steel corrosion in acid solution

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Type

Article

Created At

25 Feb 2025