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411553

Synthesis, and characterization of new Cd2+, Hg2+ complexes of thiosemicarbazone ligand derived from beta hydroxy carbonyl.

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Last updated: 15 Feb 2025

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Abstract

In this work, new Cd2+, and Hg2+ complexes of 4-pyridyl thiosemicarbazon Schiff base derived from beta-hydroxy carbonyl has been synthesized and isolated. The structure of the new complexes was proposed by numerous techniques such as elemental (CHN) analyses, FT-IR. TG and DTG thermal decomposition for Cd2+ complex was carried out. Thermodynamic and kinetic parameters were calculated via Coats-Redfern and Horowitz-Metzger equations. And finally, the modeling using DFT calculations was fully studied.

DOI

10.21608/mjcc.2023.411553

Keywords

4-pyridyl thiosemicarbazon, DFT, beta-hydroxy carbonyl

Volume

61

Article Issue

1

Related Issue

53777

Issue Date

2023-05-01

Receive Date

2025-02-13

Publish Date

2023-05-01

Page Start

38

Page End

44

Print ISSN

1687-5060

Online ISSN

2974-4938

Article File

MJCC_Volume 61_Issue 1_Pages 38-44.pdf

PDF . 1.3MB

Link

https://micc.journals.ekb.eg/article_411553.html

Detail API

http://journals.ekb.eg?_action=service&article_code=411553

Order

411,553

Type

Original Article

Type Code

3,440

Publication Type

Journal

Publication Title

Mansoura Journal of Chemistry

Publication Link

https://micc.journals.ekb.eg/

MainTitle

Synthesis, and characterization of new Cd2+, Hg2+ complexes of thiosemicarbazone ligand derived from beta hydroxy carbonyl.

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Article

Created At

15 Feb 2025