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411550

Polypodiophyta as sustainable and natural eco- friendly corrosion inhibitor of C-steel in the acidic environment: Experimental and adsorption characteristics

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Last updated: 15 Feb 2025

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Abstract

The corrosion protection of C-steel in 1 mol. L-1 HCl solutions utilized by environmentally eco-friendly green plant extract (Polypodiophyta) was demonstrated by experimental methods as chemical approaches and electrochemical techniques. The outputs indicate that C-steel in aqueous 1 M HCl solution may be effectively prevented from corroding by using the extract solution, with effectiveness of inhibition reaching 96.2% at higher dose of 300 mg L-1 and the higher applied temperature (55oC).   Polypodiophyta extract, which is consistent with Langmuir isotherm, was partially chemically adsorbed on the surface of the C-steel.  On the other hand, electrochemical results showed that polypodiophyta is efficient inhibitor with efficiency reached to 91 % at 300 mg L-1 at 25oC. Polarization research exhibits that the extract acts as mixed hindrances. With the extract double layer capacity reduces and charge transfer resistance rises in a solution of 1 mol. L-1 HCl. The outer part morphology of C-steel surfaces and the adsorption of hindrances on C-steel outer part can be checked by atomic force microscopy (AFM), and Fourier transform infrared spectroscopy (FTIR), the metal surface was developed a layer of adsorbed extract that shields it from acidic corrosion.

DOI

10.21608/mjcc.2023.411550

Keywords

C-steel, Corrosion inhibition, Polypodiophyta extract, EIS, PP, HCl, AFM, FTIR

Volume

61

Article Issue

1

Related Issue

53777

Issue Date

2023-05-01

Receive Date

2025-02-13

Publish Date

2023-05-01

Page Start

22

Page End

33

Print ISSN

1687-5060

Online ISSN

2974-4938

Link

https://micc.journals.ekb.eg/article_411550.html

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http://journals.ekb.eg?_action=service&article_code=411550

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411,550

Type

Original Article

Type Code

3,440

Publication Type

Journal

Publication Title

Mansoura Journal of Chemistry

Publication Link

https://micc.journals.ekb.eg/

MainTitle

Polypodiophyta as sustainable and natural eco- friendly corrosion inhibitor of C-steel in the acidic environment: Experimental and adsorption characteristics

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Article

Created At

15 Feb 2025