411461

Influence of Pyrolysis Temperature on the Adsorption Efficiency of Date Palm’s Petiole Biochar for N and P in Aqueous Solutions

Article

Last updated: 25 Feb 2025

Subjects

-

Tags

Agricultural productivity and contamination control of soils and water.

Abstract

The significant presence of nitrogen (N) and phosphorus (P) in wastewater poses considerable environmental challenges, including eutrophication and soil and water contamination. This research examines the adsorption efficacy of biochar produced from date palm petiole subjected to pyrolysis at temperatures of 300°C, 500°C and 700°C for the removal of nitrate (NO₃⁻), ammonium (NH₄⁺), and phosphorus (P) from aqueous environments. Characterization of the biochar revealed that increasing the pyrolysis temperature resulted in enhanced porosity, surface area, and carbon content, along with a decrease in oxygen-containing functional groups. The adsorption kinetics were most accurately represented by the pseudo-first-order model for both NO₃⁻ and P, whereas NH₄⁺ followed a pseudo-second-order model, indicative of chemisorption processes. The biochar obtained at 700°C (BC-700) exhibited the highest adsorption capacities for NH₄⁺ and P, attributable to its highly developed microporous structure and improved cation exchange capacity. Conversely, the removal of NO₃⁻ was limited across all biochar samples. The Freundlich isotherm model offered the most suitable representation of the adsorption data, indicating the presence of heterogeneous sorption sites. These results underscore the potential of pyrolyzed biochar as an environmentally sustainable adsorbent for nutrient removal from wastewater, with optimized pyrolysis conditions enhancing adsorption efficiency. However, additional investigations are warranted to augment the removal efficiency of nitrate through biochar modifications or the implementation of integrative treatment strategies.

DOI

10.21608/bct.2025.411461

Keywords

Biochar, Pyrolysis, Adsorption kinetics, nitrate, Ammonium, phosphorus, aqueous solutions

Authors

First Name

Bahaaeldein

Last Name

Khudairi

MiddleName

M.

Affiliation

Department of Soils and Water, Faculty of Agriculture, New Valley University- Egypt

Email

bahaaeldeenmahmoud@agr.nvu.edu.eg

City

New Valley

Orcid

-

First Name

Khaled

Last Name

Ibrahim

MiddleName

-

Affiliation

Department of Agronomy, Faculty of Agriculture, New Valley University

Email

k.elgeady@agr.nvu.edu.eg

City

New Valley

Orcid

https://orcid.org/00

First Name

Ahmed

Last Name

Abdelhafez

MiddleName

-

Affiliation

Department of Soils and Water Science, Faculty of Agriculture, New Valley University

Email

ahmed.aziz@agr.nvu.edu.eg

City

New Valley

Orcid

-

Volume

1

Article Issue

1

Related Issue

45973

Issue Date

2023-12-01

Receive Date

2024-12-15

Publish Date

2025-02-13

Page Start

56

Page End

71

Print ISSN

2974-3168

Online ISSN

2974-3176

Link

https://bct.journals.ekb.eg/article_411461.html

Detail API

http://journals.ekb.eg?_action=service&article_code=411461

Order

411,461

Type

Original Research Articles

Type Code

2,740

Publication Type

Journal

Publication Title

Biochar and Compost Technology

Publication Link

https://bct.journals.ekb.eg/

MainTitle

Influence of Pyrolysis Temperature on the Adsorption Efficiency of Date Palm’s Petiole Biochar for N and P in Aqueous Solutions

Details

Type

Article

Created At

15 Feb 2025