396686

EVALUATION OF SELF-HEALING CORROSION PROTECTION USING BENZOTRIAZOLE-LOADED MESOPOROUS SILICA NANOCONTAINERS FOR APPLICATION ON ARCHAEOLOGICAL BRONZE ARTEFACTS

Article

Last updated: 03 Jan 2025

Subjects

-

Tags

-

Abstract

This work evaluates the effectiveness of coating bronze coupons, with 3% Benzotriazole (BTA) -loaded nanocontainers mixed with Paraloid polymer. Mesoporous silica nanoparticles (MSNs) were prepared and loaded with 3% BTA (BTA@MSNs) followed by dispersion in 3% Paraloid B72 and B44. Bronze disc samples with the chemical composition of Cu 85%, Sn 10% and Pb 5% simulating archaeological artifacts were coated with a single and double layer of BTA@MSNs in Paraloid B72 and B44 and evaluated using several techniques. Colorimetric measurements (CM) were used to evaluate changes in the surface appearance following the coating with single and double protective layers. The corrosion inhibitive performance of the coating was investigated using electrochemical impedance spectroscopy (EIS). Transmission electron microscope (TEM) was performed to characterize the shape and size of the prepared SiO2 nanoparticles, while X-ray Diffraction (XRD) was performed to confirm the presence of amorphous mesoporous SiO2 nanoparticles. The specific surface area, pore volume and pore size distribution were measured by nitrogen adsorption– desorption technique, while the release rate of benzotriazole at various experimental pH values was estimated using UV–Vis spectroscopy. Results confirmed the sustained release of benzotriazole to varying pH levels. The release was higher with an increase in the pH of the medium, which signifies that the release rate rises in the alkaline medium. The best corrosion inhibitive performance was for the double layer BTA@MSNs – B72 samples at 91.73% efficiency, while single layer BTA@MSNs – B72 samples displayed the least change in color ΔE 3.28.

DOI

10.21608/ejars.2024.396686

Keywords

Self, healing Corrosion protection Mesoporous Silica, Nano, containers Benzotriazole Archaeological bronze Colorimetry Release study

Authors

First Name

Rifai,

Last Name

M.

MiddleName

-

Affiliation

Conservation dept., Faculty of Archaeology, Cairo Univ., Giza, Egypt

Email

-

City

-

Orcid

-

Volume

14

Article Issue

2

Related Issue

52069

Issue Date

2024-12-01

Receive Date

2023-12-01

Publish Date

2024-12-01

Page Start

199

Page End

206

Print ISSN

2090-4932

Online ISSN

2090-4940

Link

https://ejars.journals.ekb.eg/article_396686.html

Detail API

https://ejars.journals.ekb.eg/service?article_code=396686

Order

4

Type

Original Article

Type Code

575

Publication Type

Journal

Publication Title

Egyptian Journal of Archaeological and Restoration Studies

Publication Link

https://ejars.journals.ekb.eg/

MainTitle

EVALUATION OF SELF-HEALING CORROSION PROTECTION USING BENZOTRIAZOLE-LOADED MESOPOROUS SILICA NANOCONTAINERS FOR APPLICATION ON ARCHAEOLOGICAL BRONZE ARTEFACTS

Details

Type

Article

Created At

30 Dec 2024