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390859

Preparation and Characterization of Polyvinyl Alcohol /Thymol Blue/Cuprous Oxide Films Proposed for Diagnostic Radiation Detection

Article

Last updated: 01 Jan 2025

Subjects

-

Tags

Inorganic chemistry

Abstract

Background: Usage of low radiation is indispensable, hence accurate measurement became inevitable for radiation practitioners and patients. The current study presents the synthesis and characterization of polyvinyl alcohol doped with Thymol Blue and Cuprous Oxide (PVA/TB/Cu2O) as nanocomposite films for low radiation dosimetry.
Method: films prepared under controlled parameters (PVA 5%, temperature 80 ⁰C, 0.01 g of TB and 0.2 g of Cu2O). The films were irradiated with X-ray (0, 2, 4, 6, 8, 10 mGy) and evaluated using UV-spectroscope, XRD, and FTIR.
Results: UV- spectroscope for (PVA/TB) films showed absorbance peaks at l = 435, 326 and 279 nm, which de-creased as the radiation dose increased. (PVA/TB/Cu2O) films showed absorbance bands at l = 265 & 370 nm, which increased as the radiation dose increased. XRD for (PVA/TB) reveals the crystallinity of PVA at 2 thetas = 200 which increased by 55% at 10 mGy. The PVA/TB/Cu2O composite films present a prominent peak at 2 Thetas = 350, which increases following the radiation doses. The FTIR spectroscope showed chemical bonds (CH, C-O, C-O-C, CH2, C-OH, C=O, C≡N, and OH) intensities that degraded as the radiation dose increased.
Conclusion: the composite of PVA/TB ± Cu2O is utilizable for radiometer based on optical and chemical changes.

DOI

10.21608/ejchem.2024.331435.10691

Keywords

Radiation, Measurement, Diagnostic, polymer, films

Authors

First Name

Maged

Last Name

Al-Fakeh

MiddleName

S.

Affiliation

Department of Chemistry, College of Science, Qassim University, Buraidah 51452, Saudi Arabia, Taiz University, Taiz 3086, Republic of Yemen

Email

m.alfakeh@qu.edu.sa

City

Buraydah

Orcid

0000-0001-5881-4427

First Name

Mohammed Ahmed Ali

Last Name

Omer

MiddleName

-

Affiliation

Department of Radiologic Technology, College of Applied Medical Sciences, Qassim University, Buraidah, 51452, Saudi Arabia, College of Medical Radiological Sciences, Sudan University of Science & Technology, Khartoum-Sudan

Email

-

City

-

Orcid

-

First Name

Abuzar

Last Name

Albadri

MiddleName

-

Affiliation

Department of Chemistry, College of Science, Qassim University, Buraidah 51452, Saudi Arabia

Email

zarzo81@hotmail.com

City

-

Orcid

0000-0003-1167-4329

First Name

Abdulrahman A. S.

Last Name

Alsayyari

MiddleName

-

Affiliation

Department of Radiologic Technology, College of Applied Medical Sciences, Qassim University, Buraidah, 51452, Saudi Arabia

Email

-

City

-

Orcid

-

First Name

Ahmed F.

Last Name

Elhag

MiddleName

-

Affiliation

Department of Physics, College of Sciences, Qassim University, Buraidah, 51452, Saudi Arabia

Email

-

City

-

Orcid

-

Volume

67

Article Issue

12

Related Issue

50716

Issue Date

2024-12-01

Receive Date

2024-10-27

Publish Date

2024-12-01

Page Start

613

Page End

620

Print ISSN

0449-2285

Online ISSN

2357-0245

Link

https://ejchem.journals.ekb.eg/article_390859.html

Detail API

https://ejchem.journals.ekb.eg/service?article_code=390859

Order

390,859

Type

Original Article

Type Code

297

Publication Type

Journal

Publication Title

Egyptian Journal of Chemistry

Publication Link

https://ejchem.journals.ekb.eg/

MainTitle

Preparation and Characterization of Polyvinyl Alcohol /Thymol Blue/Cuprous Oxide Films Proposed for Diagnostic Radiation Detection

Details

Type

Article

Created At

30 Dec 2024