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349279

Synthesis and Evaluation of a New Chelating Agent Using Tannic Acid and Palmitic Acid of Grape Seed Oil

Article

Last updated: 01 Jan 2025

Subjects

-

Tags

Organic chemistry

Abstract

The objective of this research is to create an affordable chelating agent for eliminating heavy metals from polluted water. Water-soluble tannic acid was combined with a fatty residue to produce a new chelating agent that is soluble in hot water but insoluble in cold water due to the presence of a fatty residues that solidify at low temperatures. When this new chelating agent binds to heavy metals (HMs) in warm water, a soluble coordinating complex is formed. Lowering the water temperature causes the complex to become semi-solid and consequently insoluble, allowing for easy removal by scraping. Grape seeds (GS) were utilized as an affordable source of fatty residue. The grape seed was ground and dehydrated. The Grape seeds oil (GSO) was extracted, and hydrolyzed into a mixture of fatty acids and glycerol, followed by individual separation of palmitic acid (PA) using a supercritical carbon dioxide extractor. The produced PA was confirmed based on its chemical analysis, spectral data, and GC mass of its methyl ester. PA was then converted into the corresponding acid chloride, which was esterified with tannic acid to produce various derivatives of tannyl palmitate (TP). Tannyl tripalmitate (TTP) is the desired product, and it was separated according to its molecular weight using column and thin-layer chromatography, with a viscometer. The separated compound was established based on its chemical analyses and spectral data. Finally, TTP was evaluated as a new adsorbent for the removal of heavy metals from synthetic polluted water at different pH, doses, and time intervals. Results showed that TTP is a highly effective adsorbent for the removal of HMs from synthetic polluted water. Furthermore, a total organic carbon test (TOC) was conducted to verify the complete removal of the chelating agent and coordinating complex. The results showed complete removal of organic material from the synthetic polluted water after the scraping of the floating fatty layer.

DOI

10.21608/ejchem.2024.277730.9475

Keywords

Supercritical extractor, Heavy metals, tannyl tripalmitate, Grape seed oil, Palmitic acid, column chromatography, Chelating agent

Authors

First Name

Hanaa M.

Last Name

Soliman

MiddleName

-

Affiliation

Fats and Oils Department, Food Industries and Nutrition Research Institute, National Research Centre, 12622 Dokki, Cairo, Egypt

Email

chemist_hanaa@hotmail.com

City

-

Orcid

0000-0002-7758-3422

First Name

Usama Mohamad

Last Name

Rashad

MiddleName

-

Affiliation

Faculty of Physical Therapy Galala University..

Email

usama_elsarty@gu.edu.eg

City

-

Orcid

0000-0001-6122-2748

Volume

67

Article Issue

7

Related Issue

47288

Issue Date

2024-07-01

Receive Date

2024-03-18

Publish Date

2024-07-01

Page Start

289

Page End

299

Print ISSN

0449-2285

Online ISSN

2357-0245

Link

https://ejchem.journals.ekb.eg/article_349279.html

Detail API

https://ejchem.journals.ekb.eg/service?article_code=349279

Order

349,279

Type

Original Article

Type Code

297

Publication Type

Journal

Publication Title

Egyptian Journal of Chemistry

Publication Link

https://ejchem.journals.ekb.eg/

MainTitle

Synthesis and Evaluation of a New Chelating Agent Using Tannic Acid and Palmitic Acid of Grape Seed Oil

Details

Type

Article

Created At

30 Dec 2024