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290119

Dissipation kinetics and degradation products of cyantraniliprole in tomato plants and soil in the open field

Article

Last updated: 01 Jan 2025

Subjects

-

Tags

Environmental chemistry

Abstract

Dissipation kinetics and transformation pathways of cyantraniliprole, as a new diamide class of insecticide, are very important, since the degradation products exhibited toxicological effects and may cause more environmental hazards than the parent product. The present study was carried out to explore the fate of cyantraniliprole in tomato plants and soil under open field conditions. The determination of residues was set on HPLC Diode-Array Detection and identification of degradation products by LCMS single quadrupole mass. The dissipation rate of cyantraniliprole was ascribed to first‐order kinetics, where the rate of disappearance in tomato fruits was faster than in leaves and soil with half-lives determined to be 1.63, 5.25 and 5.92 days in tomatoes fruits, leaves and soil, respectively. The results showed that cyantraniliprole transformed into many degradation products and can be identified about 9 products. IN-J9Z38 which consider the major metabolite detected in all compartments. The detection of other degradation products varied within tomato fruits, leaves and soil. These results will help in management and establish the best scenario to minimize the adverse effects of residues and involved in risk assessment study.

DOI

10.21608/ejchem.2023.195133.7625

Keywords

Cyantraniliprole, Dissipation, Transformation products, Fate, Tomatoes, Soil

Authors

First Name

Mohamed

Last Name

Kandil

MiddleName

-

Affiliation

Entomology and Pesticide Department, Faculty of Agriculture, Cairo University, P. Box 12613, Gamma St, Giza, Egypt

Email

makandeel2003@yahoo.com

City

-

Orcid

-

First Name

Moataz

Last Name

Moustafa

MiddleName

-

Affiliation

Department of Economic Entomology and Pesticides, Faculty of Agriculture, Cairo University, 12613 Giza, Egypt.

Email

moataz.moustafa79@gmail.com

City

-

Orcid

-

First Name

Mohammed

Last Name

Saleh

MiddleName

-

Affiliation

Department of Pesticides Analysis Researches, Central Agricultural Pesticides Laboratory, Agricultural Research Center, Dokki, 12618 Giza, Egypt

Email

maasr48@yahoo.com

City

-

Orcid

-

First Name

izat

Last Name

raafat

MiddleName

-

Affiliation

Department of Pesticides Analysis Researches, Central Agricultural Pesticides Laboratory, Agricultural Research Center, Dokki, 12618 Giza, Egypt

Email

ezatraafat0@gmail.com

City

-

Orcid

-

Volume

66

Article Issue

12

Related Issue

43517

Issue Date

2023-12-01

Receive Date

2023-02-20

Publish Date

2023-12-01

Page Start

483

Page End

493

Print ISSN

0449-2285

Online ISSN

2357-0245

Link

https://ejchem.journals.ekb.eg/article_290119.html

Detail API

https://ejchem.journals.ekb.eg/service?article_code=290119

Order

290,119

Type

Original Article

Type Code

297

Publication Type

Journal

Publication Title

Egyptian Journal of Chemistry

Publication Link

https://ejchem.journals.ekb.eg/

MainTitle

Dissipation kinetics and degradation products of cyantraniliprole in tomato plants and soil in the open field

Details

Type

Article

Created At

30 Dec 2024