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274752

Electrochemical Reduction Reaction of Potassium Chromate with Orange G and Giemsa Stain Dyes in HCl Solution Using Cyclic Voltammetry and Quantum Chemistry Properties

Article

Last updated: 01 Jan 2025

Subjects

-

Tags

Analytical chemistry

Abstract

The cyclic voltammetry of potassium chromate, K2CrO4 was studied in 0.1 mol/L HCl at 291.15 and 299.15 K, respectively, using a glassy carbon electrode. The effects of various scan rates were studied in this medium. Cyclic voltammetry was also done for potassium chromate in the presence of Orange G dye at 291.15K and Giemsa stain dye at 299.15K, and further scan rate effects were discussed. The stability constants and Gibbs free energies of complexation resulting from the interaction of chromate ions with dyes were evaluated and found to be complexation reactions. All the Nicholson parameters for potassium chromate are increased by the increase of orange G or Giemsa Stain dyes concentration indicating the possibility of using this medium as a leaching solution. The molecular Gibbs free energies for potassium chromate are increased by increasing the concentration of the dyes till it reached -62.846 K.J using 2 x10-3 M Orange G dye and -44.951 K.J using 2x10-3 M Giemsa Stain dye, The stability constants and Gibbs free energy of complexation of potassium chromate with dyes are decreased by the decrease of the scan rate till they reached to 3.069 and -17.107 K.J using 2 x10-3 M Orange G dye and 5.056 and -28.961 K.J using 2x10-3 M Giemsa Stain dye for log stability constant and Gibbs free energy of complexation using scan 0.01 V/Sec scan. Molecular docking was also performed for studying the binding modes between Orange G or Giemsa Stain dyes and active sites of the structure of the SARS-CoV-2 N protein (7N0R).

DOI

10.21608/ejchem.2022.170666.7120

Keywords

electron transfer rate constant ● stability constant ● Gibbs free energy of complexation ● charge transfer coefficient ● diffusion coefficient

Authors

First Name

Marwa

Last Name

Sultan

MiddleName

S.

Affiliation

Chemistry Department, Faculty of Science, Mansoura University, Mansoura, Egypt.

Email

cute_chemist_09@yahoo.com

City

-

Orcid

-

First Name

Mohamed M.

Last Name

Eldefrawy

MiddleName

-

Affiliation

Chemistry Department, Faculty of Science, Mansoura University, Mansoura, Egypt.

Email

mmeldefrawy@hotmail.com

City

-

Orcid

-

First Name

Essam

Last Name

Gomaa

MiddleName

A.

Affiliation

Chemistry Department, Faculty of Science, Mansoura University, Mansoura, Egypt.

Email

eahgomaa65@yahoo.com

City

El-Mansoura

Orcid

0000-0002-9686-4860

Volume

66

Article Issue

9

Related Issue

43167

Issue Date

2023-09-01

Receive Date

2022-10-24

Publish Date

2023-09-01

Page Start

307

Page End

319

Print ISSN

0449-2285

Online ISSN

2357-0245

Link

https://ejchem.journals.ekb.eg/article_274752.html

Detail API

https://ejchem.journals.ekb.eg/service?article_code=274752

Order

274,752

Type

Original Article

Type Code

297

Publication Type

Journal

Publication Title

Egyptian Journal of Chemistry

Publication Link

https://ejchem.journals.ekb.eg/

MainTitle

Electrochemical Reduction Reaction of Potassium Chromate with Orange G and Giemsa Stain Dyes in HCl Solution Using Cyclic Voltammetry and Quantum Chemistry Properties

Details

Type

Article

Created At

30 Dec 2024