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269325

Synthesis of New Guanidine Benzothiazole Derivative and Its Application as Eco-Friendly Corrosion Inhibitor

Article

Last updated: 01 Jan 2025

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Tags

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Abstract

In this study, new derivatives of guanidine benzothiazole, benzo[d]thiazol-2-yl-carbamidioyl-N,N-dimethylformimidamide (GBC),was synthesized under eco-friendly procedural conditions. These derivatives showed an efficient activity as a corrosion inhibitor for carbon steel in acidic medium. The structure was confirmed using FTIR, 1HNMR and 13C NMR analysis techniques. The corrosion inhibition behavior of the synthesized compound was investigated using electrochemical techniques such as potentiodynamic polarization. Surface morphological features were studied using scanning electron microscope (SEM) coupled with (EDX). DFT theory was studied to compute theoretical parameters that related to the electronic properties of GBC and shows a good correlation with experimental data.

DOI

10.21608/ejchem.2022.167419.7063

Keywords

Guanidine benzothiazole, Potentiodynamic polarization, Scanning electron microscope, Quantum Chemical Chemistry

Authors

First Name

Amal

Last Name

Abdel-karim

MiddleName

M.

Affiliation

Physical Chemistry Department, Electrochemistry and Corrosion Lab., National Research Centre, El-Bohouth St. 33, Dokki, P.O. 12622, Giza, Egypt

Email

amalabdelkarim720@gmail.com

City

Giza

Orcid

0000-0001-9210-084x

First Name

Rasha

Last Name

Azzam

MiddleName

A.

Affiliation

Chemistry, Faculty of Science, Helwan University

Email

rashaazzam8@gmail.com

City

-

Orcid

0000-0002-6807-2110

First Name

Omnia

Last Name

El-Said Shehata

MiddleName

-

Affiliation

Physical Chemistry Department, Electrochemistry and Corrosion Lab., National Research Centre, El-Bohouth St. 33, Dokki, P.O. 12622, Giza, Egypt

Email

omniashehata@yahoo.com

City

-

Orcid

0000-0001-8134-2675

First Name

mohamed

Last Name

adly

MiddleName

A,

Affiliation

department head of khaldapetroleum company

Email

mohamed.attiaadly@yahoo.com

City

-

Orcid

-

First Name

Omnia

Last Name

El-Shamy

MiddleName

A. A.

Affiliation

Egyptian Petroleum Research Institute

Email

omniaelshamy@yahoo.com

City

-

Orcid

0000-0002-9478-4680

First Name

Gamal

Last Name

El mahdy

MiddleName

A

Affiliation

Chemistry, Faculty of Science, Helwan University

Email

gamalmah2000@yahoo.com

City

cairo

Orcid

-

Volume

66

Article Issue

7

Related Issue

42039

Issue Date

2023-07-01

Receive Date

2022-10-06

Publish Date

2023-07-01

Page Start

187

Page End

195

Print ISSN

0449-2285

Online ISSN

2357-0245

Link

https://ejchem.journals.ekb.eg/article_269325.html

Detail API

https://ejchem.journals.ekb.eg/service?article_code=269325

Order

269,325

Type

Original Article

Type Code

297

Publication Type

Journal

Publication Title

Egyptian Journal of Chemistry

Publication Link

https://ejchem.journals.ekb.eg/

MainTitle

Synthesis of New Guanidine Benzothiazole Derivative and Its Application as Eco-Friendly Corrosion Inhibitor

Details

Type

Article

Created At

30 Dec 2024