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Validation of adsorption-desorption kinetic models for fipronil and thiamethoxam agrichemicals on three types of Egyptian soils

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Last updated: 01 Jan 2025

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Abstract

To achieve the objectives of this study, the batch sorption and desorption kinetic experiments were performed to obtain the equilibrium time for fipronil and thiamethoxam in three types of Egyptian soil (clay soil, sandy clay loam soil and sandy loam soil). Equilibrium between the insecticides solution and the soil for adsorption and desorption appeared at 30, 24, 6 and 30 hr in clay soil, 0.5,12, 12 and 12 hr in sandy clay loam soil and 3, 1, 24 and 30 hr in sandy loam soil for fipronil and thiamethoxam, respectively. The adsorption rate of fipronil was higher and it had stronger affinity to three tested soils compared to thiamethoxam. Nevertheless, both pesticides showed stronger affinity to clay soil than to sandy clay loam soil and sandy loam soil. Using five kinetic models; Elovich, Intraparticle diffusion, modified Freundlich, Pseudo-first-order rate and Pseudo-second-order rate were tested to describe the experimental data.The model that gives a relatively high correlation coefficient was used to test the validity of mathematical models (R2). The best model is Pseudo-second-order rate equation that fits with experimental data for fipronil and thiamethoxam on adsorption and desorption kinetic in three types of soil (R2 ≥ 0.9). Elovich kinetic model fit the experimental data quite well for adsorption in clay soil for two insecticides, adsorption and desorption in sandy clay loam soil for thiamethoxam, adsorption in sandy loam soil for fipronil and desorption in sandy clay loam soil for thiamethoxam with high values of R2 ≥ 0.9.Its application of Intraparticle diffusion, the modified Freundlich model, and the Pseudo-first-order rate equation was limited.

DOI

10.21608/ejchem.2022.143450.6289

Keywords

Adsorption-desorption, kinetic, modeling, Soil, Fipronil, thiamethoxam

Authors

First Name

Mohamed

Last Name

Fouad

MiddleName

R.

Affiliation

Department of Pesticide Chemistry and Technology, Faculty of Agriculture, Alexandria University, Aflaton St., 21545, El-Shatby, Alexandria, Egypt.

Email

mohammed.riad@alexu.edu.eg

City

Alexandria

Orcid

0000-0002-4102-5111

Volume

66

Article Issue

4

Related Issue

40820

Issue Date

2023-04-01

Receive Date

2022-06-13

Publish Date

2023-04-01

Page Start

219

Page End

222

Print ISSN

0449-2285

Online ISSN

2357-0245

Link

https://ejchem.journals.ekb.eg/article_253011.html

Detail API

https://ejchem.journals.ekb.eg/service?article_code=253011

Order

253,011

Type

Original Article

Type Code

297

Publication Type

Journal

Publication Title

Egyptian Journal of Chemistry

Publication Link

https://ejchem.journals.ekb.eg/

MainTitle

Validation of adsorption-desorption kinetic models for fipronil and thiamethoxam agrichemicals on three types of Egyptian soils

Details

Type

Article

Created At

30 Dec 2024