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339160

Structural, Electrical, and Thermo-electric Characterization of Lightly Zn- doped PbS Films for NH3-gas Sensing

Article

Last updated: 29 Dec 2024

Subjects

-

Tags

Physics

Abstract

The lightly Zn-doped (PbS)1-x (Zn)x with x=0, 0.03, and 0.05 wt.% in thin film form were produced by thermal vacuum evaporation. The structural, morphological, and elemental composition of the thin films has been analyzed using XRD, SEM, and EDXS, respectively. The electrical conductivity and Seebeck coefficient of (PbS)1-x (Zn)x film of 200 nm thick were determined and discussed. Thin films' electrical conductivity increased with temperature and film thickness. Pure PbS films manifested a positive Seebeck coefficient value indicating a P-type semiconducting behavior. The appearance of negative S values in Zn: PbS films could be assigned to the increase in electron concentration provided by Zn-doping and refers to the change of the conduction to n-type one. Pure films possess a high majority carrier concentration of 8.07×1018 Cm-3. Zinc-metal-doped lead sulfide thin films were tested as NH3 gas sensors with 150 ppm of target gas concentration. The sensitivity of the PbS sensor to NH3 gas was determined at various gas concentrations ranging from 50 to 150 ppm. The gas sensitivity increased as concentrations increased. The best-attained results of 93% and 174s & 310s for sensitivity and response & recovery times respectively, were obtained by (PbS)0.95 (Zn)0.05 at RT.

DOI

10.21608/sjsci.2024.248570.1149

Keywords

lead sulfide thin films, response & recovery times, The electrical conductivity and Seebeck coefficient

Authors

First Name

E.

Last Name

Shokr

MiddleName

Kh.

Affiliation

Physics Department, Faculty of Science, Sohag University, Sohag 82524, Egypt

Email

eshokr@yahoo.com

City

Sohag

Orcid

-

First Name

WAEL

Last Name

Mohamed

MiddleName

S.

Affiliation

Physics Department, Faculty of Science, Sohag University, Sohag 82524, Egypt, Physics Department, College of Science, Jouf University, Al-Jouf, P.O. Box 2014, Sakaka, Saudi Arabia

Email

wael-saad@science.sohag.edu.eg

City

Sohag

Orcid

-

First Name

Ahmed

Last Name

Adam

MiddleName

G.

Affiliation

Physics Department, Faculty of Science, Sohag University, Sohag 82524, Egypt

Email

ahmed.adam@science.sohag.edu.eg

City

sohag

Orcid

-

First Name

Moumen

Last Name

Kamel

MiddleName

Samir

Affiliation

Chemistry Department, Faculty of Science, Sohag University, Sohag 82524, Egypt

Email

mim_chem2@yahoo.com

City

Sohag

Orcid

-

First Name

H.

Last Name

Ali

MiddleName

M.

Affiliation

Physics Department, Faculty of Science, Sohag University, Sohag 82524, Egypt

Email

hazem95@science.sohag.edu.eg

City

Sohag

Orcid

0000-0002-9156-7971

Volume

9

Article Issue

2

Related Issue

44506

Issue Date

2024-06-01

Receive Date

2023-11-15

Publish Date

2024-03-01

Page Start

159

Page End

166

Print ISSN

2357-0938

Online ISSN

2974-4296

Link

https://sjsci.journals.ekb.eg/article_339160.html

Detail API

https://sjsci.journals.ekb.eg/service?article_code=339160

Order

339,160

Type

Regular Articles

Type Code

2,359

Publication Type

Journal

Publication Title

Sohag Journal of Sciences

Publication Link

https://sjsci.journals.ekb.eg/

MainTitle

Structural, Electrical, and Thermo-electric Characterization of Lightly Zn- doped PbS Films for NH3-gas Sensing

Details

Type

Article

Created At

29 Dec 2024