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278823

The Crystallization Kinetic Studies of the Sn5Ge10Se85-xPbx (2.5≤x≤20 at. %) Chalcogenide Glasses

Article

Last updated: 29 Dec 2024

Subjects

-

Tags

Physics

Abstract

The topic of this article concerns the studies of the thermal analysis characterization of the Sn5Ge10Se85-xPbx (2.5≤x≤20 at. %) chalcogenide glass using the differential thermal analysis (DTA) technique. Most of the extracted kinetic parameters in this article focus on the Sn5Ge10Se82.5Pb2.5 glass. The obtained DTA thermograms emphasized one endothermic peak characterizing the glass transition process, one exothermic peak characterizing the crystallization process, and lastly, one endothermic peak characterizing the melting of the considered glass. The obtained transformation data of the mentioned glasses are analyzed using the methods of Lasocka and those based on the Johnson-Mehl-Avrami (JMA) formal theory of transformation after modification. Kissinger, Augis, and Bennett (AB), Matusita-Komatsu-Yokota (MKY), and Gao-Wang (GW) methods, in particular. Most of the deduced values of the activation energy of crystallization extracted from the used analytical methods are nearly equal. The crystalline phases of the annealed glass were detected using the X-ray diffraction (XRD) technique.  Applying the GW method, it can be emphasized that, the concerned glass is crystallized in two dimensions by surface crystallization. Besides, some of the physical parameters for the considered glass have been calculated, which can be used to ascertain the obtained experimental data. In this context, the average coordination number (Z), the deviation of stoichiometry (r), the fraction of floppy (f), and the overall mean bond energy (˂E˃) have been calculated.

DOI

10.21608/sjsci.2023.172603.1043

Keywords

Sn5Ge10Se85-xPbx, chalcogenide glass, differential thermal analysis, crystallization kinetics

Authors

First Name

M.

Last Name

Wakkad

MiddleName

M.

Affiliation

Physics Department, Faculty of Science, Sohag University, Sohag 82524, Egypt

Email

mostafa.wakkad@yahoo.com

City

sohag

Orcid

-

First Name

M.

Last Name

Abd El-Raheem

MiddleName

M.

Affiliation

Physics Department, Faculty of Science, Sohag University, Sohag 82524, Egypt

Email

elneh_55@science.sohag.edu.eg

City

sohag

Orcid

-

First Name

H.

Last Name

Mohamed

MiddleName

A.

Affiliation

Physics Department, Faculty of Science, Sohag University, Sohag 82524, Egypt

Email

hussein_abdelhafez2000@yahoo.com

City

Sohag

Orcid

-

First Name

N.

Last Name

Hamed

MiddleName

I.

Affiliation

Physics Department, Faculty of Science, Sohag University, Sohag 82524, Egypt

Email

nadaayman.0195@gmail.com

City

Sohag

Orcid

-

Volume

8

Article Issue

2

Related Issue

38751

Issue Date

2023-05-01

Receive Date

2022-11-03

Publish Date

2023-05-01

Page Start

163

Page End

174

Print ISSN

2357-0938

Online ISSN

2974-4296

Link

https://sjsci.journals.ekb.eg/article_278823.html

Detail API

https://sjsci.journals.ekb.eg/service?article_code=278823

Order

278,823

Type

Regular Articles

Type Code

2,359

Publication Type

Journal

Publication Title

Sohag Journal of Sciences

Publication Link

https://sjsci.journals.ekb.eg/

MainTitle

The Crystallization Kinetic Studies of the Sn5Ge10Se85-xPbx (2.5≤x≤20 at. %) Chalcogenide Glasses

Details

Type

Article

Created At

29 Dec 2024