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394024

Modelling the sorption behaviour of heavy elements on soil

Article

Last updated: 29 Dec 2024

Subjects

-

Tags

Meteorology and Physics

Abstract

A laboratory experiment was conducted to examine, compare and evaluate the sorption of heavy metals (nickel and lead) on sorbent materials (sandy and sandy loam soils). The sorption data were fitted with some sorption isotherm models using the software IsoFit such as Linear, Freundlich, and proposed new model. Measured and simulated data were compared statistically to evaluate model reliability. It noticed that the sorption of Ni and Pb was more pronounced in sandy loam soil than in sandy soil and the sorption percentage was decreased by increasing the initial concentration. The results showed that the average values of sorption percentages of sandy and sandy loam soils were 80.39 and 87.69% and 87.23 and 93.89% for Ni and Pb, respectively. Also, the experimental data was analyzed to examine the adsorption isotherm models. The distribution coefficients (Kd) obtained from the linear sorption isotherm model were 98.772 and 168.524 L/kg (as Ni and Pb) for sandy soil and 161.606 and 388.391 L/kg (as Ni and Pb) for sandy loam soil. Metals can be arranged according to their Kd values, i.e. their affinities for the soil, in the following relative sequence: Pb> Ni. This general sequence tends to vary slightly for different soil types. The obtained results are promising and useful in industrial wastewater infiltration into the soil profile and groundwater. In conclusion, understanding the sorption dynamics of heavy metals in soil systems is essential for managing contaminated sites and protecting environmental health. This research recommends future studies to verify the competitive mechanism of heavy metals sorption correlated to the soil characteristic parameters.

DOI

10.21608/ajsws.2024.327476.1020

Keywords

heavy metals sorption, IsoFit software, Adsorption, sorption isotherm models

Authors

First Name

Ola

Last Name

Elhetamy

MiddleName

Mohammed

Affiliation

Soil and Agricultural Chemistry Dept., Faculty of Agriculture Saba Basha Alexandria University Egypt

Email

myalhtmy@gmail.com

City

-

Orcid

-

First Name

Gamal

Last Name

Khalil

MiddleName

Abdel-Nasser

Affiliation

Faculty of Agriculture Saba Basha Bolkely P.O. 21531

Email

nasserga@gmail.com

City

Alexandria

Orcid

0000-0002-1078-2398

First Name

Adel

Last Name

Hussein

MiddleName

Hussein

Affiliation

Soil and Agricultural Chemistry Dept., Faculty of Agriculture Saba Basha, Alexandria University, EGYPT

Email

ahahmed_61@yahoo.com

City

-

Orcid

-

First Name

wafaa

Last Name

H. M. Ali

MiddleName

-

Affiliation

Soil

Email

-

City

-

Orcid

-

Volume

9

Article Issue

1

Related Issue

50869

Issue Date

2025-01-01

Receive Date

2024-11-03

Publish Date

2025-01-01

Page Start

24

Page End

35

Print ISSN

2357-0598

Online ISSN

2785-9959

Link

https://ajsws.journals.ekb.eg/article_394024.html

Detail API

https://ajsws.journals.ekb.eg/service?article_code=394024

Order

394,024

Type

Research papers

Type Code

2,302

Publication Type

Journal

Publication Title

Alexandria Journal of Soil and Water Sciences

Publication Link

https://ajsws.journals.ekb.eg/

MainTitle

Modelling the sorption behaviour of heavy elements on soil

Details

Type

Article

Created At

29 Dec 2024