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332907

Chemical characterization of phosphogypsum produced from raw phosphate rock from the phosphoric acid manufacturing process

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Last updated: 05 Jan 2025

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Abstract

Phosphorgypsum (an industrial by-product) is formed during the production of fertilizers and phosphoric acid from raw phosphate. It consists primarily of CaSO4 and contains impurities Zn, Pb, Cu, Cd, Ni, Cr, and many rare earth elements such as lanthanum and cerium.
The current article aims to study the chemical elemental content of phosphoric gypsum, and the results showed that the percentage of P2O5 in phosphoric gypsum is 2.7%, and the main component is calcium sulphate, with a percentage of 68.5%.
As for the element content, the concentrations of Cr, La, Ni, Ce, Pb, Cd l are explained in the research, and the reason for their presence is due to their transfer during the phosphoric acid manufacturing process from raw phosphate to phosphate by the wet method. As for the chemical elemental content of the raw phosphate taken, which was determined using AAS atomic absorption technology, , Cr, Pb, Cd respectively (9.2, 13.5, 10, 4.58, 0.46, 7.02) ppm.
The ETF values ​​showed a high transition rate for both cerium and lanthanum, reaching 72.59% for cerium and 68.47% for lanthanum. In general, it is noted that the largest percentage of lanthanides (cerium and lanthanium) was transferred to the phosphogypsum resulting from the manufacture of phosphoric acid by the wet method, while the highest percentage of P2O5 was transferred to the phosphoric acid formed.

DOI

10.21608/hiss.2023.332907

Keywords

: lanthanium, raw phosphates, Cerium, phosphogypsum

Authors

First Name

Nada

Last Name

Hasan

MiddleName

-

Affiliation

Department of chemistry, Faculty of Education for Girls, University of Kufa,Najaf, Iraq.

Email

nadah.alsherify@uokufa.edu.iq

City

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Orcid

-

Volume

3

Article Issue

16

Related Issue

45078

Issue Date

2023-07-01

Receive Date

2023-12-29

Publish Date

2023-07-01

Page Start

4,971

Page End

4,989

Print ISSN

2786-0256

Online ISSN

2786-0264

Link

https://hiss.journals.ekb.eg/article_332907.html

Detail API

https://hiss.journals.ekb.eg/service?article_code=332907

Order

332,907

Type

البحوث والدِّراسات.

Type Code

1,961

Publication Type

Journal

Publication Title

مجلة المعهد العالي للدراسات النوعية

Publication Link

https://hiss.journals.ekb.eg/

MainTitle

Chemical characterization of phosphogypsum produced from raw phosphate rock from the phosphoric acid manufacturing process

Details

Type

Article

Created At

28 Dec 2024