Beta
281269

Investigating the Structural and Dielectric Properties of La-doped PbLaxTi(1-3/4x)O3 Perovskite Ceramics: The Role of La Content

Article

Last updated: 28 Dec 2024

Subjects

-

Tags

Research and articles conducted by or in which members of the teaching staff

Abstract

In this study, PbLaxTi(1 - 3/4 x)O3 (PLT) ceramics were prepared using the tartrate precursor method with varying La content (x= 0, 0.04, and 0.1). The samples were annealed at 600°C and characterized using X-ray diffraction, Fourier-transform infrared spectroscopy, high-resolution transmission electron microscopy and dielectric measurements. The results showed that all samples doped with La ions had a first-order structural phase transition from tetragonal to cubic at the Curie temperature (Tc). This phase transition was also associated with a transition from ferroelectric to paraelectric phase. The dielectric spectra revealed that the material displayed relaxer-type ferroelectric behavior, with Tc shifting to a higher value and dielectric constant increasing with increasing La content up to x=0.04. The increase in dielectric constant was attributed to the decrease in grain size in the given range of La content. Furthermore, La doping in lead titanate (PT) led to the formation of A-site vacancies, which affected the Curie temperature and the atomic radius between La and Pb ions. This study highlights the potential of using La ions as a dopant in PT ceramics to improve their ferroelectric properties, specifically by inducing a relaxor behavior.

DOI

10.21608/djs.2023.187668.1073

Keywords

Perovskite structure, Lead titanate, La-ions, Ferroelectric materials

Authors

First Name

Mohamed

Last Name

Salem

MiddleName

-

Affiliation

Physics department, Faculty of science, Tanta university.

Email

elshshtawy@science.tanta.edu.eg

City

-

Orcid

0000-0001-8822-8613

First Name

Eman

Last Name

Serag

MiddleName

N.

Affiliation

Physics Department, Faculty of science, Tanta university.

Email

eman.sarag@must.edu.eg

City

-

Orcid

-

First Name

Osama

Last Name

Hemeda

MiddleName

M.

Affiliation

Physics Department, Faculty of science, Tanta university.

Email

omhemeda@yahoo.co.uk

City

-

Orcid

-

First Name

Aseel

Last Name

Altarawneh

MiddleName

M.

Affiliation

Physics Department, Faculty of science, Tanta university.

Email

aseelt682@gmail.com

City

-

Orcid

-

First Name

A.

Last Name

Henaish

MiddleName

M. A.

Affiliation

Physics Department, Faculty of science, Tanta university.

Email

ahmed.henaish@science.tanta.edu.eg

City

-

Orcid

-

First Name

sayed

Last Name

Abdelgawad

MiddleName

Ahmed

Affiliation

Basic science,Faculty of Engineering MUST University, Cairo, Egypt.

Email

sayed.shama@must.edu.eg

City

-

Orcid

-

Volume

46

Article Issue

1

Related Issue

39472

Issue Date

2023-02-01

Receive Date

2023-01-15

Publish Date

2023-02-01

Page Start

58

Page End

68

Print ISSN

1012-5965

Online ISSN

2735-5306

Link

https://djs.journals.ekb.eg/article_281269.html

Detail API

https://djs.journals.ekb.eg/service?article_code=281269

Order

5

Type

Research and Reference

Type Code

1,686

Publication Type

Journal

Publication Title

Delta Journal of Science

Publication Link

https://djs.journals.ekb.eg/

MainTitle

Investigating the Structural and Dielectric Properties of La-doped PbLaxTi(1-3/4x)O3 Perovskite Ceramics: The Role of La Content

Details

Type

Article

Created At

28 Dec 2024