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362742

Mechanistic deterioration by saponification of a 17th Century Oil Painting from the Museum of Modern Art in Cairo

Article

Last updated: 25 Dec 2024

Subjects

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Tags

CONSERVATION AND RESTORATION

Abstract

Metal soap plays a role in the deformation, fading, deterioration and cracking of oil paint layers as a result of the paintings being exposured to unsuitable environmental conditions.  This leads to the interaction of metal ions with free fatty acids resulting from the hydrolysis of glycerides in the oil medium, or from protective varnish and forming metal soap, which catalyzes the hydrolysis of triglycerides in the oil medium and frees fatty acids. The decomposition of the medium then occurs and results in metal carboxylate, inside the coating film and precipitate on the surface of the painting, leading to damage. The mechanism of damage to oil paintings with lead-containin.g soap, characterized by long-chain elements of alkanes or chain soaps of lead (II), from octanoate to octadecenoate, has been analyzed using a 17th century oil painting from the Museum of Modern Art in Cairo. The analysis used a wide range of examination and analytical methods such as FTIR, Raman Spectroscopy, SEM-EDS, XRD, Gas chromatography (GC-MS), scanning electron microscopy, stereomicroscope, and examination with polarizing microscopy after making cross-sections. This is so that targeted strategies can be developed to slow deterioration at that particular stage and help determine the state of preservation of the artworks

DOI

10.21608/shedet.2024.362742

Authors

First Name

Thanaa

Last Name

Ali

MiddleName

-

Affiliation

Faculty of Archaeology, Aswan University, Egypt

Email

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City

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Orcid

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Volume

13

Article Issue

13

Related Issue

48692

Issue Date

2024-08-01

Receive Date

2024-06-30

Publish Date

2024-06-01

Page Start

315

Page End

334

Print ISSN

2356-8704

Online ISSN

2536-9954

Link

https://shedet.journals.ekb.eg/article_362742.html

Detail API

https://shedet.journals.ekb.eg/service?article_code=362742

Order

362,742

Publication Type

Journal

Publication Title

Shedet

Publication Link

https://shedet.journals.ekb.eg/

MainTitle

Mechanistic deterioration by saponification of a 17th Century Oil Painting from the Museum of Modern Art in Cairo

Details

Type

Article

Created At

25 Dec 2024