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390752

Metal-Organic Frameworks (MIL-100 (Fe)) for commercial reactive dye effluent oxidation

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Last updated: 24 Dec 2024

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Abstract

Urgent calls for scientists' contributions towards saving eco-system from toxic deterioration. Such ever increasing urgency is leading the researchers for searching for ever greening technologies such as advanced oxidation processes for aqueous effluent elimination. This current investigation is leading to investigate the metal organic frameworks, role, MIL-100(Fe) that is prepared from reacting H3BTC and ferric nitrate nona hydrate Also, Scanning electron microscopy is applied to set the surface shape of the synthesized substance. Subsequently, the prepared MIL-100(Fe) is used to oxidize Procion Blue MX-7RX in aqueous solution as a model textile wastewater effluent. The catalyst is applying in Fenton's oxidation system and operating parameters that affecting the system is evaluated. The experimental results revealed that 40 and 800 mgL-1 for MIL-100(Fe) and hydrogen peroxide, respectively at pH 3.0 that is leading to a complete dye removal (100%). Furthermore, the dye loading affects the reaction rate since its increase reduces the removal efficacy. Finally, thermodynamic parameters and kinetics of the reaction is evaluated for the scale-up purposes for real applications.

DOI

10.1088/1742-6596/2830/1/012019

Keywords

MOF, Oxidation, Textile effluent wastewater, Modified Fenton’s system

Authors

First Name

Eman

Last Name

Genena

MiddleName

E.

Affiliation

Chemistry department, Faculty of Science, Menoufia University, Shebin El-Kom, Egypt., Advanced Materials/Solar Energy and Environmental Sustainability (AMSEES) Laboratory, Basic Engineering Science Department, Faculty of Engineering, Menoufia University, Shebin El-Kom, Egypt.

Email

eman.genena.eg@gmail.com

City

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Orcid

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First Name

Ibrahim

Last Name

El-Sayed

MiddleName

E.T.

Affiliation

Chemistry department, Faculty of Science, Menoufia University, Shebin El-Kom, Egypt.

Email

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City

-

Orcid

-

First Name

Ahmed

Last Name

Abou-Elyazed

MiddleName

S.

Affiliation

Chemistry department, Faculty of Science, Menoufia University, Shebin El-Kom, Egypt., Institute of Intelligent Manufacturing Technology, Shenzhen Polytechnic University, Shenzhen 518055, China.

Email

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City

-

Orcid

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First Name

Hamed

Last Name

Abdel-Bary

MiddleName

M.

Affiliation

Chemistry department, Faculty of Science, Menoufia University, Shebin El-Kom, Egypt.

Email

-

City

-

Orcid

-

First Name

Maha

Last Name

Abdelbaset

MiddleName

-

Affiliation

Advanced Materials/Solar Energy and Environmental Sustainability (AMSEES) Laboratory, Basic Engineering Science Department, Faculty of Engineering, Menoufia University, Shebin El-Kom, Egypt.

Email

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City

-

Orcid

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Volume

11

Article Issue

11

Related Issue

51450

Issue Date

2024-03-01

Receive Date

2024-11-06

Publish Date

2024-03-01

Page Start

1

Page End

8

Print ISSN

2636-4336

Online ISSN

2636-4344

Link

https://iccee.journals.ekb.eg/article_390752.html

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https://iccee.journals.ekb.eg/service?article_code=390752

Order

390,752

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Original Article

Type Code

832

Publication Type

Journal

Publication Title

The International Conference on Chemical and Environmental Engineering

Publication Link

https://iccee.journals.ekb.eg/

MainTitle

Metal-Organic Frameworks (MIL-100 (Fe)) for commercial reactive dye effluent oxidation

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Article

Created At

24 Dec 2024