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302122

Assessment of antioxidant resistance to thermal - oxidative degradation of stabilized polybutadiene binder

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Last updated: 04 Jan 2025

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Abstract

polybutadiene is the most common polymeric binder for composite solid propellants. This polymer suffers from oxidative degradation reactions on storing with deterioration in mechanical properties. Certain anti-oxidant materials can retard such reaction offering enhanced aging characteristics. In this study, two different primary antioxidants including phenol-based (AO2246) and amine-based (Flexzone 6H) were employed to stabilize polybutadiene polymer. Oxidation induction time (OIT) was evaluated using isothermal DSC. High OIT value means high resistance to oxidative degradation. The impact of anti-oxidant on mechanical properties was evaluated using shore A. Flexzone 6H significantly improved binder oxidative stability with an increase in OIT value by 20 folds with significant decrease in oxidation enthalpy. Flexzone 6H can offer enhanced resistance toward oxidative reactions; as it can act as efficient H atom donor to break down chain degradation reaction. Additionally, the three stabilized aromatic rings can capture free radicals. AO2246 enhanced the binder mechanical characteristics during aging at 80 0C using Shore A test. In the meantime, AO2246 could enhance the mechanical properties due to its integration into the polymeric matrix due to –OH functional groups. The two anti-oxidants demonstrated controversy effects. Whereas Flexzone 6H offered enhanced resistance to oxidative degradation; AO2246 offered enhanced mechanical properties.

DOI

10.1088/1757-899X/975/1/012006

Authors

First Name

Eslam

Last Name

Elsaka

MiddleName

-

Affiliation

School of chemical Engineering, Military Technical College, Cairo, Egypt.

Email

eng.elsaka12@gmail.com

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First Name

Sherif

Last Name

Elbasuney

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-

Affiliation

Head of Nanotechnology Research Center, Military Technical College (MTC), Egyptian Armed Forces, Cairo, Egypt.

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Orcid

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First Name

Ahmed

Last Name

Elbeih

MiddleName

-

Affiliation

School of chemical Engineering, Military Technical College, Cairo, Egypt.

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City

-

Orcid

-

First Name

Hosam

Last Name

Mostafa

MiddleName

E.

Affiliation

School of chemical Engineering, Military Technical College, Cairo, Egypt.

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City

-

Orcid

-

First Name

Mahmoud

Last Name

Awad

MiddleName

E.

Affiliation

School of chemical Engineering, Military Technical College, Cairo, Egypt.

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-

City

-

Orcid

-

First Name

Tarek

Last Name

Elhedery

MiddleName

M.

Affiliation

School of chemical Engineering, Military Technical College, Cairo, Egypt.

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-

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-

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Volume

10

Article Issue

10

Related Issue

41655

Issue Date

2020-07-01

Receive Date

2023-06-05

Publish Date

2020-07-01

Page Start

1

Page End

9

Print ISSN

2636-4336

Online ISSN

2636-4344

Link

https://iccee.journals.ekb.eg/article_302122.html

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https://iccee.journals.ekb.eg/service?article_code=302122

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302,122

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Original Article

Type Code

832

Publication Type

Journal

Publication Title

The International Conference on Chemical and Environmental Engineering

Publication Link

https://iccee.journals.ekb.eg/

MainTitle

Assessment of antioxidant resistance to thermal - oxidative degradation of stabilized polybutadiene binder

Details

Type

Article

Created At

24 Dec 2024