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347254

Electrodialysis and electrodialysis reversal for the concentration of Li containing solutions

Article

Last updated: 24 Dec 2024

Subjects

-

Tags

Chemical Engineering

Abstract

In this paper, the application of electrodialysis reversal (EDR) in the recovery and concentration of lithium chloride and lithium carbonate solutions is described. Both salts are raw materials that can be used for the production of lithium ion batteries. EDR is characterized by a periodical change of electric polarity and hydraulic flows. This allows the minimization of scaling effects and concentration polarization on the membrane surface during the treatment of lithium containing brines or solutions stemming from lithium ion battery recycling. Lab scale investigations at room temperature were conducted during which the concentrated solution was kept in the cycle throughout the respective investigations, and the diluted solution was exchanged, when a minimum conductivity of 0.08 mS/cm was reached. At the same time, the polarity was changed and the hydraulic flows were reversed. A comparison between EDR and conventional ED at the same operating conditions showed similar current efficiencies of up to 70 % during the concentration of lithium chloride. A maximum lithium chloride concentration in the concentrate solution of about 25 g/l was achieved. The investigations showed the general applicability of EDR for the concentration of lithium chloride and lithium carbonate, which has a restricted solubility in water. Generally, EDR could play a major role in lithium ion battery recycling.

DOI

10.21608/pserj.2024.244808.1275

Keywords

Circular Economy, ED, EDR, ion exchange membranes, Li recovery

Authors

First Name

Frank

Last Name

Roegener

MiddleName

-

Affiliation

Chemical Process Engineering and Plant Design TH Koeln - University of Applied Sciences

Email

frank.roegener@th-koeln.de

City

Cologne

Orcid

0000-0002-6012-0958

First Name

Christoph

Last Name

Manderscheid

MiddleName

-

Affiliation

Chemical Process Engineering and Plant Design TH Koeln - University of Applied Sciences

Email

christoph.manderscheid@th-koeln.de

City

Cologne

Orcid

-

Volume

28

Article Issue

2

Related Issue

47541

Issue Date

2024-05-01

Receive Date

2023-12-05

Publish Date

2024-05-01

Page Start

1

Page End

8

Print ISSN

1110-6603

Online ISSN

2536-9377

Link

https://pserj.journals.ekb.eg/article_347254.html

Detail API

https://pserj.journals.ekb.eg/service?article_code=347254

Order

1

Type

Original Article

Type Code

813

Publication Type

Journal

Publication Title

Port-Said Engineering Research Journal

Publication Link

https://pserj.journals.ekb.eg/

MainTitle

Electrodialysis and electrodialysis reversal for the concentration of Li containing solutions

Details

Type

Article

Created At

24 Dec 2024