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287061

Test Method Validation for Quantitative Determination of Heavy Metals in Olive Oils by Inductive Coupled Plasma (ICP – AES) using Low Cost and Simple Extraction Method

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Last updated: 24 Dec 2024

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Abstract

ABSTRACT     The aim of this study is to demonstrate a valid and simple extraction method for the extraction of heavy metals from olive oil and its quantitative determination by ICP-AES technique. Fifteen olive oil samples are collected from different manufacturing companies originates from five countries. Fourteen metals are quantitively detected in all samples including; Aluminum, Arsenic, Calcium, Cadmium, Cobalt, Chromium, Copper, Iron, Potassium, Magnesium, Manganese, Nickel, Lead and Zinc. A simple extraction method has been proposed for the extraction of heavy metals from the raw oil samples based on diluted 10% HNO3. Test method validation procedures have been carried out for the quantitative analytical determination of the detected trace metals in the investigated oil samples. The trace elements are found to be in the concentration range from 0.0001 to 8.39 mg.kg-1. As a result of the test method validation; linearity (R2) is above 0.99, the recovery ranged between (72.63% to 124.62%), the limit of detection and the limit of quantitation are between (0.006– 2.32 µg.kg-1) and (0.022 – 7.68 µg.kg-1) respectively. The relative standard deviation (RSDs) for repeatability and ruggedness are found to be lower than 2.2% for selected elements, which confirms the precision of the ICP-AES analytical method. The results demonstrate the validity of accurate, precise, rugged, selective, specific and stable ICP-AES determination method for trace metal analysis in raw olive oil samples that based on the proposed simple extraction method.      

DOI

10.21608/jesr.2023.287061

Keywords

Key words : Heavy metals, ICP-AES, olive oil, method validation

Authors

First Name

Hagag

Last Name

S

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Affiliation

Nano-Photochemistry and its Environmental Applications Laboratory, Environmental Studies and Research Institute (ESRI), University of Sadat City, Sadat City, 32897 Menofia, Egypt

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First Name

Mona

Last Name

Saif

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Affiliation

Department of Chemistry, Faculty of Education, Ain Shams University, Roxy, 11711 Cairo, Egypt.

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First Name

Hoda

Last Name

H. S

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-

Affiliation

Nano-Photochemistry and its Environmental Applications Laboratory, Environmental Studies and Research Institute (ESRI), University of Sadat City, Sadat City, 32897 Menofia, Egypt

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Volume

10

Article Issue

4

Related Issue

39819

Issue Date

2020-12-01

Receive Date

2023-02-22

Publish Date

2020-12-01

Page Start

1,248

Page End

1,262

Print ISSN

2356-8054

Online ISSN

2785-9770

Link

https://jesr.journals.ekb.eg/article_287061.html

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https://jesr.journals.ekb.eg/service?article_code=287061

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Original Article

Type Code

800

Publication Type

Journal

Publication Title

Journal of Environmental Studies and Researches

Publication Link

https://jesr.journals.ekb.eg/

MainTitle

Test Method Validation for Quantitative Determination of Heavy Metals in Olive Oils by Inductive Coupled Plasma (ICP – AES) using Low Cost and Simple Extraction Method

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Article

Created At

24 Dec 2024