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Leaching of rare earth elements from phosphate rock using sulfuric acid: Process optimization and kinetic studies

Article

Last updated: 04 Jan 2025

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Abstract

Rare earth elements (REEs) are crucial raw materials for ‘smart' electronic devices and emerging renewable energy resources.  Accordingly, the global attention for the secondary REEs resources such as phosphate rock is increased.  Recognizing effective leaching of REEs from phosphate rock is essential from a strategic perspective for addressing the world demand highly growth rate.  The present study investigates the leaching of REEs from phosphate rock using sulfuric acid.  The impact of the main variables on the leaching performance was examined.  Design of experiments (DoE) methodology was applied for optimization the REEs leaching process.  The anticipated data declare that about 96.6% leaching percent could be achieved according to the following conditions: 1.5 M sulfuric acid concentration, 30 mL/ g as liquid/ solid ratio, 55 oC reaction temperature and stirring time of 1.0 hr. shrinking core model (SCM) was applied to explore the kinetic attitude of REEs leaching process.  The exhibited results deduced that leaching process is well depicted using the ash layer diffusion kinetic model.  In addition, the activation of energy of REEs leaching process was found to be equal 9.01 kJ/mol.

DOI

10.21608/nssj.2023.237144.1013

Keywords

Rare earth elements, phosphate rock, sulfuric acid, process optimization, leaching kinetic

Authors

First Name

WALID

Last Name

YOUSSEF

MiddleName

M.

Affiliation

Nuclear Materials Authority

Email

m.walid_nma@yahoo.com

City

-

Orcid

-

First Name

OSAMA

Last Name

ROSHDY

MiddleName

E.

Affiliation

Nuclear Materials Authority

Email

-

City

-

Orcid

-

First Name

MAHMOUD

Last Name

EL-MAADAWY

MiddleName

M.

Affiliation

Nuclear Materials Authority

Email

-

City

-

Orcid

-

First Name

WAEL

Last Name

ELMAADAWY

MiddleName

M.

Affiliation

Nuclear Materials Authority

Email

-

City

-

Orcid

-

First Name

MOHAMED

Last Name

TAHA

MiddleName

H.

Affiliation

Nuclear Materials Authority

Email

-

City

-

Orcid

-

Volume

12

Article Issue

1

Related Issue

43073

Issue Date

2023-08-01

Receive Date

2023-09-17

Publish Date

2023-08-01

Page Start

51

Page End

65

Print ISSN

2314-5609

Link

https://nssj.journals.ekb.eg/article_330777.html

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https://nssj.journals.ekb.eg/service?article_code=330777

Order

330,777

Type

Original Article

Type Code

798

Publication Type

Journal

Publication Title

Nuclear Sciences Scientific Journal

Publication Link

https://nssj.journals.ekb.eg/

MainTitle

Leaching of rare earth elements from phosphate rock using sulfuric acid: Process optimization and kinetic studies

Details

Type

Article

Created At

24 Dec 2024