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327190

Application and Theoretical Study: New Barbiturate Derivatives as Corrosion Inhibitors

Article

Last updated: 03 Jan 2025

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Abstract

The study's focus is on the use of potentiostat technology to stop the corrosion of mild steel alloys using various barbiturates which are newly prepared compounds. It has been synthesized and described by 13C, FTIR, and 1HNMR techniques at concentrations ranging from 0 to 200 ppm in a 1M sulfuric acid solution at temperatures between 303 and 323 K. Anode and cathode curves (a, c), corrosion current density (Icorr), corrosion potential (Ecorr), and efficiency inhibition ratio (E%) were used in the experiments, and the results were presented.DFT calculations have been performed to understand the nature of the interactions between the inhibitor molecules and the surface of the alloy to be tested.
             The influence of temperature and concentration on the effectiveness of inhibition was examined. The prepared compound used as an inhibitor is effective and a good corrosion inhibitor in mild steel alloy under the experimental conditions used, where the highest inhibition efficiency was 85.30% at a rising temperature and increasing inhibitor concentration, according to the results. 200ppm concentration at 323K in temperature. were also examined and talked about. it was found that the adsorption of the two compounds obeys Langmuir, which elaborated the thermodynamic functions of the adsorption operation  (ΔSads, ΔHads, ΔGads).

DOI

10.21608/eajbsc.2023.327190

Keywords

Thermodynamic functions, Alloys, Corrosion, Barbiturates, Adsorption isotherm, Potentiometry, cathodic inhibitors

Authors

First Name

Kadhim

Last Name

Ali

MiddleName

A.

Affiliation

Department of Chemistry, College of Education for Pure Sciences, University of Karbala, Karbala, Iraq.

Email

-

City

iraq

Orcid

-

First Name

Mohanad

Last Name

Kareem

MiddleName

M.

Affiliation

Department of Chemistry, College of Science, University of Babylon, P.O. Box 51002, Hilla, Iraq.

Email

sci.mohanad.mousa@uobabylon.edu.iq

City

Iraq

Orcid

-

First Name

Hamida

Last Name

Salman

MiddleName

I.

Affiliation

Department of Chemistry, College of Education for Pure Sciences, University of Karbala, Karbala, Iraq.

Email

hamida.idan@uokerbala.edu.iq

City

Iraq

Orcid

-

Volume

15

Article Issue

2

Related Issue

42345

Issue Date

2023-12-01

Receive Date

2023-10-16

Publish Date

2023-11-28

Page Start

723

Page End

735

Print ISSN

2090-0767

Online ISSN

2090-083X

Link

https://eajbsc.journals.ekb.eg/article_327190.html

Detail API

https://eajbsc.journals.ekb.eg/service?article_code=327190

Order

327,190

Type

Original Article

Type Code

673

Publication Type

Journal

Publication Title

Egyptian Academic Journal of Biological Sciences. C, Physiology and Molecular Biology

Publication Link

https://eajbsc.journals.ekb.eg/

MainTitle

Application and Theoretical Study: New Barbiturate Derivatives as Corrosion Inhibitors

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Article

Created At

24 Dec 2024