Industrial solid waste accumulation poses a great hazard for the environment. The aim of this work was the utilization of alum waste produced from the production of Alum {Al₂(SO₄)₃} using kaolin to produce sodium aluminate and sodium silicate. This was carried out by the leaching of calcined Alum waste using several acids (H₂SO₄, HCl, HNO₃) with different concentrations (2, 4, 6, 8 and 10 M) at 90 ^oC for 2 hrs to achieve maximum Al₂O₃ recovery followed by filtration process. The filtrate (concentrated Al₂O₃) was treated with NaOH to produce sodium aluminate while the precipitate (concentrated SiO₂) was treated with NaOH to produce Sodium Silicate via two different processes. The first process was by fusing the precipitate with NaOH with ratio 1:1 to 1:5 (Solid: NaOH) at 60 ^oC followed by dissolving in water at 60 ^oC. The second process was by treating the precipitate with several NaOH concentrations (1, 2, 3, 4, 5 M) at 90 ^oC for varying times (1, 2, 3 hrs). Results showed that maximum Al₂O₃ recovery was achieved with 10M H₂SO₄ leaching at 90 ^oC for 3hrs (89.28 %) which is used to produce Sodium Aluminate. Sodium Aluminate solution was dried at 130-150 ^oC and analyzed using X-Ray diffraction (XRD). Sodium Silicate was produced with SiO₂/Na₂O weight ratio (WR) from 2.15 to 3.44 in the first process while was nearly 2 in the second process.