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300229

The Efficiency of Using Na EDTA and DTPA to Extract Different Fractions of Soil Strontium

Article

Last updated: 01 Jan 2025

Subjects

-

Tags

Soil microbiology, chemistry and biochemistry

Abstract

Strontium takes the same uptake and distribution pathways of Ca within plants; hence disturbs many secondary metabolites. In humans, it can replace Ca in bones and teeth, making them brittle. Thus, remediating Sr-polluted soils has become an obligation to attain a hazard-free environment. In this context, Sr is one of the potentially toxic elements that have received little attention. Thus, the current study aims at investigating the efficiency of using different chelating agents i.e. Na EDTA and DTPA for the chemical extraction of Sr from contaminated soils. To attain this aim, three soil types i.e. a clay loam one and two sandy loam soils varying in their CaCO3 content were artificially polluted with Sr at three levels (50, 100 and 200 mg Sr kg-1); then left to equilibrate for 3 months. Thereafter, Sr was determined within the different soil fractions. In the clayey soil, most Sr was bounded with sesquioxide; followed by the exchangeable fraction, while in the other two soils (sandy loam ones), most of soil-Sr dominated within the exchangeable form, followed by the carbonate bound fraction. The contaminated soils were then subjected to soil leaching via either Na EDTA or DTPA and the extractable amount by both methods were comparable, with slight superiority for DTPA. Generally, the extraction efficiencies of Sr by these chelating agents were low in the sandy loam soils which contained 50 mg Sr kg-1 while increased considerably with increasing the level of soil contamination recording approximately 76-88%. Afterward, fractionation of Sr was accomplished again where the carbonate and organic bound fractions were the dominant ones; yet the exchangeable fraction still represents a substantial percentage. Generally, all fractions prior to soil leaching were correlated with each other. The two chelating agents were capable of extracting Sr among the different soil fractions except for the sesquioxide bound which was not extractable by Na-EDTA (r2=0.371) yet it can be extracted by DTPA (r2=0.413). This result provides more evidence for the feasibility of using both EDTA-2Na and DTPA in the chemical extraction of Sr from contaminated soils.

DOI

10.21608/ejss.2023.208549.1589

Keywords

Strontium, soil polluting, chemical extraction, Na-EDTA, DTPA

Authors

First Name

Ihab

Last Name

Farid

MiddleName

M

Affiliation

Benha University, Faculty of Agriculture, Soils and Water Department

Email

ihabfarid2005@yahoo.com

City

-

Orcid

-

First Name

Magdy

Last Name

Ahmed

MiddleName

-

Affiliation

Nuclear Research Center, Egyptian Atomic Energy Authority EAEA, Inshas, Egypt

Email

magdyamr@yahoo.com

City

-

Orcid

-

First Name

Mohamed

Last Name

Abbas

MiddleName

H.H.

Affiliation

Benha University, Faculty of Agriculture, Soils and Water department

Email

mohamed.abbas@fagr.bu.edu.eg

City

Obour

Orcid

0000-0002-1905-1241

First Name

Amal

Last Name

Elshazly

MiddleName

-

Affiliation

Nuclear Research Center, Egyptian Atomic Energy Authority EAEA, Inshas, Egypt

Email

amal.shazly@yahoo.com

City

-

Orcid

-

Volume

63

Article Issue

3

Related Issue

42643

Issue Date

2023-09-01

Receive Date

2023-05-02

Publish Date

2023-09-01

Page Start

277

Page End

286

Print ISSN

0302-6701

Online ISSN

2357-0369

Link

https://ejss.journals.ekb.eg/article_300229.html

Detail API

https://ejss.journals.ekb.eg/service?article_code=300229

Order

2

Type

Original Article

Type Code

19

Publication Type

Journal

Publication Title

Egyptian Journal of Soil Science

Publication Link

https://ejss.journals.ekb.eg/

MainTitle

The Efficiency of Using Na EDTA and DTPA to Extract Different Fractions of Soil Strontium

Details

Type

Article

Created At

23 Dec 2024