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285283

Evaluating the removal efficiency of potentially toxic elements (PTEs) from a shale deposit by citric acid

Article

Last updated: 01 Jan 2025

Subjects

-

Tags

Soil degradation control, remediation and reclamation

Abstract

The majority of arable lands of Egypt are deserts, mainly sandy soils of low fertility, low water retention and high water and wind erodibility. Shale deposits (rich in clay minerals) might be considered suitable conditioners to improve soil physical, chemical and mineralogical properties and hence increase its productivity. However, these additives should not be a source of contaminants such as PTEs. Accordingly, a technical shale deposit sample was collected from Abu Thor (longitudes between 33○ 22″ and 33○ 23ʺ E and latitudes between 29○ 00″ and 29○ 02ʺ N), Southwest Sinai . In this shale deposit sample, silica comprised 37.35% and alumina was about 18.37%. This sample also contained 630 mg Mn, 7704 mg Zn, 19200 mg Fe, 2627 mg Pb, 2763 mg Co and 1310 mg Ni per kg. These levels are not environmentally acceptable in shale deposits when used for soil conditioning. Accordingly, removal or at least reduction in contents of these contaminants in shale deposits should be considered prior to their addition as conditioners to low fertile which exhibit low water holding soils such as the sandy ones. To attain this aim, PVC columns (6.8cm inner diameter× 45cm height) were filled with the shale deposit, washed with citric acid (conc: 10 g L-1) at a flow rate of 1 mL per min. with a total volume of 3200 mL per column and the leachate was collected every 100 min to determine its content of PTEs. Cumulative extracted PTEs were calculated versus time and best fitted to the power function kinetic model. This extraction followed the sequence of Ni>Fe>Co>Pb≈Zn>Mn and, in general, the removal efficiencies were low and did not exceed 12% of Ni, 4% of Co, 2.97% of Mn, 2% of Pb and 1% for each of Fe and Zn. It can; therefore, be deduced that citric acid can only chelate the easily bounded forms of PTEs. More researches are needed to investigate the efficiency of citric acid for in-situ long term facilitated phytoextraction of PTEs from shale deposits to attain more acceptable levels

DOI

10.21608/ejss.2023.148878.1567

Keywords

potentially toxic elements, Citric acid, Removal efficiency, Extraction, desorption kinetics

Authors

First Name

Ali

Last Name

Ali

MiddleName

-

Affiliation

Nuclear Materials Authority

Email

alidarwesh888@gmail.com

City

-

Orcid

-

First Name

Ihab

Last Name

Farid

MiddleName

M

Affiliation

Benha University, Faculty of Agriculture, Soils and Water Department

Email

ihabfarid2005@yahoo.com

City

-

Orcid

-

First Name

Mohamed

Last Name

Abbas

MiddleName

H.H.

Affiliation

Benha University, Faculty of Agriculture, Soils and Water department

Email

mohamed.abbas@fagr.bu.edu.eg

City

Obour

Orcid

0000-0002-1905-1241

Volume

63

Article Issue

2

Related Issue

39925

Issue Date

2023-06-01

Receive Date

2023-01-16

Publish Date

2023-06-01

Page Start

143

Page End

150

Print ISSN

0302-6701

Online ISSN

2357-0369

Link

https://ejss.journals.ekb.eg/article_285283.html

Detail API

https://ejss.journals.ekb.eg/service?article_code=285283

Order

285,283

Type

Original Article

Type Code

19

Publication Type

Journal

Publication Title

Egyptian Journal of Soil Science

Publication Link

https://ejss.journals.ekb.eg/

MainTitle

Evaluating the removal efficiency of potentially toxic elements (PTEs) from a shale deposit by citric acid

Details

Type

Article

Created At

23 Dec 2024