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374449

Successive Recovery of Uranium and Valuable Elements from Mineralized Dolostone, Gabal Alluga, Southwestern Sinai, Egypt

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Last updated: 29 Dec 2024

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Abstract

The present work was conducted in two stages of leaching processes, stage one, an
alkaline leaching of uranium and zinc from Alluga rock sample, Sinai area, using sodium
hydroxide solution. The leaching conditions, including sodium hydroxide concentration, stirring
time, temperature and liquid-solid ratio were studied. The optimum conditions were sodium
hydroxide concentration (5mol/L), stirring time (180 min), liquid-solid ratio (4/1) and
temperature (70oC), the leaching efficiency was about 91.2% for uranium and 93.5% for zinc.
 The second stage took place on the spent residue left behind for leaching the rare earth
elements using mixture of sulfuric acid and magnesium sulfate solution, the optimum conditions
were achieved at sulfuric acid concentration (1mol/L), magnesium sulfate concentration (0.8
mol/L), temperature (200o C), stirring time (120 min), and liquid-solid ratio (3/1), under these
conditions leaching efficiency of rare earth was 96.5%. The experimental leaching kinetic data
of uranium, zinc and rare earth elements were well identified by a shrinking core model with
diffusion control through a product layer, with apparent activation energies of 8.74 KJ/mol for
uranium, 21.3 KJ/mol for zinc and 18.26 KJ/mol for rare earth elements. 

DOI

10.21608/jbes.2024.374449

Keywords

recovery, Uranium, zinc, REEs, Kinetic modeling, Shrinking core models

Authors

First Name

Fatma S.

Last Name

Hassen

MiddleName

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Affiliation

Nuclear Materials Authority, P.O. Box 530 El-Maadi, Cairo, Egypt

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Volume

11

Article Issue

1

Related Issue

49699

Issue Date

2024-01-01

Receive Date

2024-08-17

Publish Date

2024-01-01

Page Start

143

Page End

165

Print ISSN

2536-9202

Online ISSN

2356-6388

Link

https://jbes.journals.ekb.eg/article_374449.html

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https://jbes.journals.ekb.eg/service?article_code=374449

Order

374,449

Type

Original Article

Type Code

3,063

Publication Type

Journal

Publication Title

Journal of Basic and Environmental Sciences

Publication Link

https://jbes.journals.ekb.eg/

MainTitle

Successive Recovery of Uranium and Valuable Elements from Mineralized Dolostone, Gabal Alluga, Southwestern Sinai, Egypt

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Article

Created At

21 Dec 2024