Beta
371131

Characterization and Application of Olive Stones Activated Carbon for Uranium (VI) Sorption from Wet-process phosphoric acid: Kinetic, equilibrium and thermodynamic studies

Article

Last updated: 29 Dec 2024

Subjects

-

Tags

-

Abstract

In this work, uranium adsorption from Egyptian phosphoric acid onto chemical modified Olive Stones has been
studied by two methods (H3PO4 and ZnCl2) at 800ºC was used to carbonized. The relevant factors affecting uranium
adsorption onto our Olive Stones Activated Carbon adsorbent were studied. These factors involved phosphoric acid
concentration, the contact time, adsorbent weight, initial uranium concentration and the temperature were investigated.
The theoretical capacity of Olive Stones Activated Carbon adsorbent is about (47.8, 46.08) mg/g for O.S-H3PO4, O.SZnCl2 respectively. The optimum adsorption conditions were choiced in two methods and P2O5 ineffective by these
conditions. The sorption process of uranium U(VI) follow Langmuir isotherm model with pseudo-second order
mechanism and exothermic nature and spontaneous process according to studying (enthalpy change, entropy change and
Gibbs free energy change). More Than 80 % of the loaded uranium amount on the Olive Stones Activated Carbon
adsorbent has been eluted using 0.1 M HNO3 as an efficient eluent. 

DOI

10.21608/jbes.2020.371131

Keywords

Activated carbon, Olive stone, uranium U(VI), H3PO4, ZnCl2, sorption

Authors

First Name

Walid M.

Last Name

Youssef

MiddleName

-

Affiliation

Nuclear Materials Authority, P.O. Box 530, El-Maadi, Cairo, Egypt

Email

-

City

-

Orcid

-

Volume

7

Article Issue

1

Related Issue

49587

Issue Date

2020-01-01

Receive Date

2024-07-31

Publish Date

2020-01-01

Page Start

1

Page End

12

Print ISSN

2536-9202

Online ISSN

2356-6388

Link

https://jbes.journals.ekb.eg/article_371131.html

Detail API

https://jbes.journals.ekb.eg/service?article_code=371131

Order

371,131

Type

Original Article

Type Code

3,063

Publication Type

Journal

Publication Title

Journal of Basic and Environmental Sciences

Publication Link

https://jbes.journals.ekb.eg/

MainTitle

Characterization and Application of Olive Stones Activated Carbon for Uranium (VI) Sorption from Wet-process phosphoric acid: Kinetic, equilibrium and thermodynamic studies

Details

Type

Article

Created At

21 Dec 2024