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370591

Dissolution Kinetics of Lanthanides from Abu Tartur Phosphate Rocks, with Tartaric acid

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Last updated: 29 Dec 2024

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Abstract

Phosphate rock is one of the most important REEs secondary resources. Accordingly, this work focuses on the selective
leaching of REES from Abu-Tartur phosphate rock using Tartaric acid solution. The influence of various factors affecting the
leaching process such as reaction time, acid concentration, liquid/solid mass ratio, reaction temperature and stirring speed
were thoroughly studied to estimate the favor REEs dissolution in relation to P2O5. The leaching data shows that 90.5 and
26.8 % of REEs and P2O5 respectively could be leached from phosphate rock after 60 min using 1.0 M Tartaric acid and 5/ 1
liquid/ solid, mL/ g, ratio at room temperature with mechanical stirring of 300 rpm. The application of graphical and
statistical approaches for the analysis of kinetic data revealed that the rate of REEs leaching from Abu-Tartur phosphate rock
using Tartaric acid is determined by the ash layer diffusion step. The apparent activation energy for the dissolution process
was calculated as 12.43 kJ/mol. The dissolution process could be expressed by the following semi-empirical kinetic equation:
[1 āˆ’ 3(1 āˆ’š›¼)
2
3 + 2(1 āˆ’ š›¼)] = 0.22 š‘’
āˆ’12431ā„š‘…š‘‡ļæ½

DOI

10.21608/jbes.2019.370591

Keywords

Dissolution kinetic, Lanthanides, Abut-Tartur, Phosphate rocks, Tartaric acid

Authors

First Name

M. F.

Last Name

Kamel

MiddleName

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Affiliation

Nuclear Materials Authority. P.O. Box 530, El Maddi, Cairo, Egypt

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Orcid

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First Name

S. A.

Last Name

Mohamed

MiddleName

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Affiliation

Chemistry Department, Faculty of Science, Ain Shams University

Email

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City

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Orcid

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First Name

H. I.

Last Name

Mira

MiddleName

-

Affiliation

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Email

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City

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Orcid

-

First Name

M.H.

Last Name

Taha

MiddleName

-

Affiliation

Nuclear Materials Authority. P.O. Box 530, El Maddi, Cairo, Egypt

Email

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City

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Orcid

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First Name

A. M.

Last Name

Masoud

MiddleName

-

Affiliation

Nuclear Materials Authority. P.O. Box 530, El Maddi, Cairo, Egypt

Email

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City

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Orcid

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First Name

A. E. M.

Last Name

Hussein

MiddleName

-

Affiliation

Nuclear Materials Authority. P.O. Box 530, El Maddi, Cairo, Egypt

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Volume

6

Article Issue

2

Related Issue

49538

Issue Date

2019-04-01

Receive Date

2024-07-29

Publish Date

2019-04-01

Page Start

78

Page End

87

Print ISSN

2536-9202

Online ISSN

2356-6388

Link

https://jbes.journals.ekb.eg/article_370591.html

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https://jbes.journals.ekb.eg/service?article_code=370591

Order

370,591

Type

Original Article

Type Code

3,063

Publication Type

Journal

Publication Title

Journal of Basic and Environmental Sciences

Publication Link

https://jbes.journals.ekb.eg/

MainTitle

Dissolution Kinetics of Lanthanides from Abu Tartur Phosphate Rocks, with Tartaric acid

Details

Type

Article

Created At

21 Dec 2024