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370479

The potential of nitrate removal from groundwater of Bani-Suif west area, Egypt using nanocomposite reverse osmosis membranes

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Last updated: 21 Dec 2024

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Abstract

The excessive use of nitrogen-based fertilizers during flood irrigation, pesticide, waste disposal and industrial waste,
seepage from septic tanks and evaporation processes during flood irrigation affects to the extent onto the groundwater
quality of the shallow Quaternary aquifer of Bani-Suif west area, Egypt. A combination of major, heavy metals and
nitrate has been used to characterize the groundwater in the investigated area. For this aspect, thirteen groundwater
samples belong to that aquifer were collected. The total dissolved salts were varied between 327 and 2436 mg/l. Despite,
the majority of the groundwater salinity was under the permissible limit for drinking, it was found to be unsuitable for
human drinking, where they have had high concentrations of nitrate, which ranges from 366.41 to 1535.9 mg/l
(exceeding the permissible limit, 45 mg/l). Because the aquifer has a high potentiality of groundwater, therefore, it is a
must to re-use this high quantity of groundwater. Membrane technology was found to be the most suitable technique to
overcome this problem. Therefore, three different types of thin film composite membranes (PA, PA/SiO2, and PA/SW- CNT's) were prepared using the interfacial polymerization technique. The change of surface morphology of membranes
because of addition of nanomaterials was characterized using Scanning Electron Microscopy, where the surface of the
nanocomposite membranes was shown to be rougher than the unmodified membrane. In addition, the membranes were
tested with a cross-flow apparatus to determine their performance in terms of water flux, salt rejection, and nitrate
removal. However, the nanomaterials have been added to enhance the membrane water flux and even the salt rejection. It
was observed that; nitrate rejection was shown to be decreased in the order of PA/SW-CNT's > PA/SiO2 > PA. Where,
PA/SW-CNTs reduced the nitrate concentration of a natural groundwater sample from 366.41 to 21.98 mg/l, i.e. under
the permissible limit.

DOI

10.21608/jbes.2018.370479

Keywords

Nitrate Removal, Groundwater, TFC membranes, silica, carbon nanotubes

Authors

First Name

Mohamed E. A.

Last Name

Ali

MiddleName

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Affiliation

Egyptian Desalination Research Center of Excellence & Hydrogeochemistry Dept., Desert Research Center, 1-Mathaf El-Mataryia St., Cairo, 11753, Egypt,

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First Name

Abdel-Hameed M.

Last Name

El-Aassar

MiddleName

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Affiliation

Egyptian Desalination Research Center of Excellence & Hydrogeochemistry Dept., Desert

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Volume

5

Article Issue

3

Related Issue

49528

Issue Date

2018-07-01

Receive Date

2024-07-29

Publish Date

2018-07-01

Page Start

230

Page End

239

Print ISSN

2536-9202

Online ISSN

2356-6388

Link

https://jbes.journals.ekb.eg/article_370479.html

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https://jbes.journals.ekb.eg/service?article_code=370479

Order

370,479

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Original Article

Type Code

3,063

Publication Type

Journal

Publication Title

Journal of Basic and Environmental Sciences

Publication Link

https://jbes.journals.ekb.eg/

MainTitle

The potential of nitrate removal from groundwater of Bani-Suif west area, Egypt using nanocomposite reverse osmosis membranes

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Article

Created At

21 Dec 2024