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148863

Dielectric Modulus Relaxation and Hopping Conduction Mechanism of Bisphenol A Corncobs Polycarbonate

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Last updated: 23 Jan 2023

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Abstract

Dielectric relaxation of bisphenol A corncobs polycarbonate (BPACC)
has been studied in the temperature and frequency ranges of 310-400K and
100Hz-4MHz, respectively. A clear r, a, a' and b-relaxation processes are
observed in these studied ranges of temperature and frequency. An analysis of
the dielectric constant, e', and the dielectric loss index, e", was performed
assuming a distribution of relaxation times as confirmed by the behavior of
electric modulus spectra. The calculated activation energy, Ea, are 0.36eV,
0.17eV, and 0.09eV for a, a' and b-relaxation processes, respectively. The
behavior of ac conductivity, sac, of BPACC sample revealed that the relaxation
occurs as a result of charge carriers between localized states. The conduction
mechanism of BPACC sample is controlled by the correlated barrier hopping
model (CBH).

DOI

10.21608/ejs.2011.148863

Volume

34

Article Issue

1

Related Issue

21881

Issue Date

2011-12-01

Receive Date

2010-06-16

Publish Date

2011-12-01

Page Start

93

Page End

107

Print ISSN

1012-5566

Online ISSN

2735-5640

Link

https://ejs.journals.ekb.eg/article_148863.html

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https://ejs.journals.ekb.eg/service?article_code=148863

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Journal

Publication Title

Egyptian Journal of Solids

Publication Link

https://ejs.journals.ekb.eg/

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Article

Created At

23 Jan 2023