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139436

Spectroscopic studies on the interaction between thioglycolic acid (TGA)- capped CdTe quantum dots and cyanine dyes

Article

Last updated: 05 Jan 2025

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Abstract

Three different particle sizes from cadmium telluride semiconductor quantum dots (CdTe QDs)
have been prepared using thioglycolic acid as a capping agent in aqueous media. The photophysical behavior
for these particles has been studied in presence of monomethine dyes belong to thiazole orange (TO) family.
The aggregation of the cyanine dyes on QDs surface was attributed to the presence of electrostatic attraction
between negatively charged thioglycolic capping molecules and the ionic dye. Energy transfer process from
CdTe QDs to cyanine dyes was also studied using electronic absorption and steady state emission
measurements. The energy transfer parameters such as Stern- Volmer rate constants Ksv, binding sites n,
quenching sphere radius "r", critical energy transfer distance "R0" and the efficiency of energy transfer E, have
been calculated. The enhancement in the triplet state emission and absorption for the studied dye in the
presence of QDs was expected to play a role in molecular oxygen sensitization and photodynamic therapy
(PDT) as well as photovoltaic applications.

DOI

10.21608/djs.2017.139436

Keywords

CdTe, Quantum dots, thiazole, Quenching

Authors

First Name

Mostafa F.

Last Name

Abdelbar

MiddleName

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Affiliation

Chemistry Department, Faculty of Science, Tanta University, Tanta, Egypt

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First Name

Tarek A.

Last Name

Fayed

MiddleName

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Affiliation

Chemistry Department, Faculty of Science, Tanta University, Tanta, Egypt

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First Name

Talaat M.

Last Name

Meaz

MiddleName

-

Affiliation

Physics Department, Faculty of Science, Tanta University, Tanta, Egypt

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First Name

El- Zeiny M.

Last Name

Ebeid

MiddleName

-

Affiliation

Misr University for Science and Technology (MUST), 6th of October City, Egypt

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Orcid

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Volume

38

Article Issue

1

Related Issue

20623

Issue Date

2017-06-01

Receive Date

2021-01-14

Publish Date

2017-06-01

Page Start

115

Page End

137

Print ISSN

1012-5965

Online ISSN

2735-5306

Link

https://djs.journals.ekb.eg/article_139436.html

Detail API

https://djs.journals.ekb.eg/service?article_code=139436

Order

12

Type

Research and Reference

Type Code

1,686

Publication Type

Journal

Publication Title

Delta Journal of Science

Publication Link

https://djs.journals.ekb.eg/

MainTitle

Spectroscopic studies on the interaction between thioglycolic acid (TGA)- capped CdTe quantum dots and cyanine dyes

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Article

Created At

23 Jan 2023