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228553

Fabrication, Structural and Adsorption Studies of Zirconium Oxide Nanoparticles

Article

Last updated: 28 Dec 2024

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Abstract

The current research presents the fabrication of zirconium oxide by using a precipitation method followed by
calcination at 400 oC for 2 h. The calcined powder was confirmed by different tools such as X-ray diffraction
(XRD), Fourier transform infrared spectra (FT-IR), Field emission scanning electron microscope (FE-SEM) and
transmission electron microscope (TEM). The XRD results revealed that the average crystallite size of the
fabricated zirconium oxide nanoparticles was 5 nm. FTIR spectra showed the peak at 450 cm-1 corresponding to
the crystalline ZrO2 nanoparticles. The effect of contact time, initial dye concentration, adsorbent dosage and pH
was studied. The adsorption data fitted the pseudo-first-order kinetic model. The adsorption followed Langmuir
adsorption isotherm model compared to the freundlich isotherm model. Thermodynamic parameters for the
adsorption system were showed that the adsorption process is spontaneous, physiorption and endothermic. The
prepared product has efficient adsorption performance to naphthol green B dye (NGB) with a maximum adsorption
capacity of 51.54 mg.g–1.

DOI

10.21608/bjas.2020.228553

Keywords

Zirconium oxide nanoparticles, precipitation method, Adsorption, Structural, Naphthol green B dye

Authors

First Name

A.A.

Last Name

Ali

MiddleName

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Affiliation

Chemistry Dept., Faculty of Science, Benha Univ., Benha, Egypt

Email

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City

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Orcid

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First Name

S.A.

Last Name

Shama

MiddleName

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Affiliation

Chemistry Dept., Faculty of Science, Benha Univ., Benha, Egypt

Email

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City

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Orcid

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First Name

S.R.

Last Name

EL-Sayed

MiddleName

-

Affiliation

Chemistry Dept., Faculty of Science, Benha Univ., Benha, Egypt

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City

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Orcid

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Volume

5

Article Issue

Issue 7 part (1) - (2)

Related Issue

20337

Issue Date

2020-10-01

Receive Date

2020-10-31

Publish Date

2020-10-01

Page Start

245

Page End

253

Print ISSN

2356-9751

Online ISSN

2356-976X

Link

https://bjas.journals.ekb.eg/article_228553.html

Detail API

https://bjas.journals.ekb.eg/service?article_code=228553

Order

36

Type

Original Research Papers

Type Code

1,647

Publication Type

Journal

Publication Title

Benha Journal of Applied Sciences

Publication Link

https://bjas.journals.ekb.eg/

MainTitle

Fabrication, Structural and Adsorption Studies of Zirconium Oxide Nanoparticles

Details

Type

Article

Created At

23 Jan 2023