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160749

Evaluation of analytical method for determination of tetracyclines in their dosage forms by HPLC using different types of chromatographic stationary phases (RP-C8 and RP-C18)

Article

Last updated: 28 Dec 2024

Subjects

-

Tags

Animal Health

Abstract

Antibiotics are extensively used in animal husbandry practices for the treatment of diseases. Four tetracyclines are commercially available as veterinary medicines, of which oxytetracycline (OTC), tetracycline (TC), chlortetracycline (CTC), and doxycycline (DOX). In the present investigation, a novel simple, sensitive, and inexpensive method of analysis was verified for tetracyclines by RP-HPLC system in bulk drug substance and pharmaceutical forms via two stationary phases (C8 & C18). The separation was attained on a 250 mm column length, 4.6 mm internal diameter, 5 µm particle size, C18 and C8 columns with a (55:25:20) 5% glacial acetic acid: acetonitrile: methanolic acid as elution solution at a 355 nm wavelength. The method was performed at a 0.8 ml/min flow rate. This method was applied without an extraction process. The method was validated following ICH and USP guidelines. It was proved to be reproducible and more economical due to the short retention time of less than 6 min by C8 column and 8 min by C18 column which enabled analysis of tetracycline pharmaceutical products with a relatively lower volume of mobile phase. The result of formulation analysis was statistically validated with a high recovery percentage. Furthermore, the developed method was free from the interference of excipients used in the formulation. The validated method was accurate, precise, linear, and reproducible. The data suggest the possibility of using the method in quality control laboratories with better routine analysis of tetracyclines in their dosage forms.

DOI

10.21608/ejah.2021.160749

Keywords

Tetracyclines, HPLC, drugs, RP-C8, RP-C18

Volume

1

Article Issue

2

Related Issue

23581

Issue Date

2021-04-01

Receive Date

2021-01-12

Publish Date

2021-04-01

Page Start

1

Page End

10

Print ISSN

2735-4938

Online ISSN

2735-4946

Link

https://ejah.journals.ekb.eg/article_160749.html

Detail API

https://ejah.journals.ekb.eg/service?article_code=160749

Order

1

Type

Original researches

Type Code

1,636

Publication Type

Journal

Publication Title

Egyptian Journal of Animal Health

Publication Link

https://ejah.journals.ekb.eg/

MainTitle

Evaluation of analytical method for determination of tetracyclines in their dosage forms by HPLC using different types of chromatographic stationary phases (RP-C8 and RP-C18)

Details

Type

Article

Created At

23 Jan 2023