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127584

Kinetics of uranium leaching process using sulfuric acid for Wadi Nasib ore, South western Sinai, Egypt

Article

Last updated: 28 Dec 2024

Subjects

-

Tags

Environmental chemistry
Environmental management

Abstract

The leaching of uranium from Wadi Nasib ore using sulfuric acid solution has been studied. The effect of different parameters such as leaching time, sulfuric acid concentration, solid/liquid ratio, leaching temperature and mechanical stirring speed were investigated in order to optimize various process parameters for maximizing the recovery of uranium. Uranium dissolution efficiency of 98.5% was obtained for Wadi Nasib ore after 4 hours contact time leaching using 200 g L-1 H2SO4 and solid/liquid ratio 1/4 at leaching temperature 80°C and 400 rpm mechanical stirring speed without any oxidant addition. The kinetic data showed that the leaching process can be described by a shrinking-core model with apparent activation energy equals to 16.2 kJ/mol. The low activation energy supported the findings that the Wadi Nasib leaching rate is controlled by diffusion-controlled process.

DOI

10.21608/aujes.2020.127584

Keywords

kinetic, Leaching, Uranium ore, sulfuric acid, Diffusion Control

Authors

First Name

S.A.

Last Name

Zakia

MiddleName

-

Affiliation

Nuclear Materials Authority, P.O. Box 530 El Maadi, Cairo, Egypt

Email

salah.afify@yahoo.com

City

-

Orcid

-

First Name

M.M.

Last Name

Rashad

MiddleName

-

Affiliation

Nuclear Materials Authority, P.O. Box 530 El Maadi, Cairo, Egypt

Email

-

City

-

Orcid

-

First Name

S.A.

Last Name

Mohamed

MiddleName

-

Affiliation

Chemistry Department, Faculty of Science, Menofiya University

Email

-

City

-

Orcid

-

First Name

E.M.

Last Name

EL sheikh

MiddleName

-

Affiliation

Nuclear Materials Authority, P.O. Box 530 El Maadi, Cairo, Egypt

Email

-

City

-

Orcid

-

First Name

H.E.

Last Name

Mira

MiddleName

-

Affiliation

Nuclear Materials Authority, P.O. Box 530 El Maadi, Cairo, Egypt

Email

-

City

-

Orcid

-

First Name

G.M.

Last Name

Abd el Wahab

MiddleName

-

Affiliation

Nuclear Materials Authority, P.O. Box 530 El Maadi, Cairo, Egypt

Email

-

City

-

Orcid

-

Volume

1

Article Issue

2

Related Issue

18654

Issue Date

2020-12-01

Receive Date

2020-09-05

Publish Date

2020-12-01

Page Start

171

Page End

182

Print ISSN

2735-4229

Online ISSN

2735-4237

Link

https://aujes.journals.ekb.eg/article_127584.html

Detail API

https://aujes.journals.ekb.eg/service?article_code=127584

Order

5

Type

Original Research

Type Code

1,615

Publication Type

Journal

Publication Title

Aswan University Journal of Environmental Studies

Publication Link

https://aujes.journals.ekb.eg/

MainTitle

Kinetics of uranium leaching process using sulfuric acid for Wadi Nasib ore, South western Sinai, Egypt

Details

Type

Article

Created At

23 Jan 2023