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124651

Polymer Complexes. LVI. Supramolecular Architectures Consolidated by Hydrogen Bonding and p-p Interaction.

Article

Last updated: 22 Jan 2023

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Tags

Mathematics and Engineering Physics

Abstract

In this study, amidation of aliphatic amine with acryloyl chloride in the dry benzene as solvent has been prepared. Moreover, the polymer complexes have been prepared. All compounds have been characterized by the analytical, spectroscopic ( IR, UV, NMR, ESR) and thermal methods. Addition, the magnetic susceptibility and molar conductance measurements have been made. Acryloylhydrazin (AH) has been shown to behave as a bidentate logand via its nitrogen (of the NH; of hydrazine group) and C-O/ C=0 (of the acryloyl group) in polymer complexes, all of which exhibit supramolecular architectures assembled through weak interaction including hydrogen bonding and 1- 1 stacking The magnetic and spectral data indicate a square planar geometry for Cu2+ complex and an octahedral geometry for Co(II) and UO2 (II). The ESR spectral data of the Cu(II) complexes showed that the metal-ligand bonds have considerable covalent character. The thermal stability was investigated using thermogravimetric analysis. The results showed that the polymer complexes are more stable than the homopolymer.

DOI

10.21608/bfemu.2020.124651

Keywords

Poly(acryloylhydrazin) homopolymer, supramolecular polymer complexes, and thermal analysis

Authors

First Name

A.

Last Name

El-Sonbati

MiddleName

Z.

Affiliation

Chemistry Department, Faculty of Science (Demiatta), Mansoura University, Demiatta, Egypt.

Email

elsonbatisch@yahoo.com

City

Demiatta

Orcid

-

First Name

M.

Last Name

Diab

MiddleName

A.

Affiliation

Chemistry Department, Faculty of Science (Demiatta), Mansoura University, Demiatta, Egypt.

Email

-

City

Demiatta

Orcid

-

First Name

A.

Last Name

Belal

MiddleName

A. M.

Affiliation

Chemistry Department, Faculty of Science, Port Said University, Egypt

Email

-

City

Port Said

Orcid

-

First Name

M.

Last Name

Attallah

MiddleName

E.

Affiliation

Chemistry Department, Faculty of Science (Demiatta), Mansoura University, Demiatta, Egypt.

Email

-

City

Demiatta

Orcid

-

Volume

35

Article Issue

2

Related Issue

18139

Issue Date

2010-06-01

Receive Date

2010-04-19

Publish Date

2020-11-21

Page Start

12

Page End

21

Print ISSN

1110-0923

Online ISSN

2735-4202

Article File

BFEMU_Volume 35_Issue 2_Pages 12-21.pdf

PDF . 1.0MB

Link

https://bfemu.journals.ekb.eg/article_124651.html

Detail API

https://bfemu.journals.ekb.eg/service?article_code=124651

Order

10

Type

Research Studies

Type Code

1,205

Publication Type

Journal

Publication Title

MEJ. Mansoura Engineering Journal

Publication Link

https://bfemu.journals.ekb.eg/

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-

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Article

Created At

22 Jan 2023