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211132

Using Examination Methods and EDX Analysis to Study the Archaeological Vitreous Enamels

Article

Last updated: 25 Dec 2024

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Abstract

This study aims to examine and analyse different samples of vitreous enamel from two objects: one in Aljazeera Museum and the other in the Faculty of Applied Arts' Museum in Cairo, Egypt. The applied enamel decoration incorporates two sophisticated methods of enamelling: champlevé and peinture enamel, which are important techniques in enamel decoration, applied onto a metal substrate. Seven samples of different enamel colours were studied, examination was performed using a stereo and digital microscope to document the enamel surface and identify the most important deterioration aspects of enamel, which vary between pitting, cracking, separation, micro-cracks, scratches and loss of enamel........etc.
The chemical composition of both types of enamel was identified using (SEM−EDX). The results proved that the enamel contains basically silicon, potassium, sodium, and lead. These enamels are classified as soda-potash glass or mixed alkaline glass. The results also proved that the colouring agents in both types of enamel are copper oxide used to produce translucent green enamel, cobalt oxide for translucent dark blue enamel, copper oxide with more sodium and potassium oxide for opaque turquoise enamel. A thin layer of gold was used under the translucent enamel to obtain the red enamel (this is an ancient technique for obtaining different shades of transparent enamel), and arsenic oxide for opaque white enamel. Moreover, the results proved that the chemical composition of enamels date back to the 19th century.

DOI

10.21608/arcs.2021.88897.1017

Keywords

enamel, Champlevé, Peinture, examination, EDX

Authors

First Name

Wafaa

Last Name

Anwer

MiddleName

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Affiliation

Conservation Department, Faculty of Archaeology, Cairo University, Giza, Egypt 12613

Email

wafaaanw@yahoo.com

City

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Orcid

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First Name

Niazy

Last Name

Mostafa

MiddleName

-

Affiliation

Ministry of Tourism and Antiquities, Cairo, Egypt

Email

niazymostafa_re@yahoo.com

City

-

Orcid

-

Volume

2

Article Issue

2

Related Issue

29691

Issue Date

2021-12-01

Receive Date

2021-08-14

Publish Date

2021-12-28

Page Start

25

Page End

34

Print ISSN

2682-3454

Online ISSN

2682-3462

Link

https://arcs.journals.ekb.eg/article_211132.html

Detail API

https://arcs.journals.ekb.eg/service?article_code=211132

Order

3

Type

Original Article

Type Code

1,070

Publication Type

Journal

Publication Title

Advanced Research in Conservation Science

Publication Link

https://arcs.journals.ekb.eg/

MainTitle

Using Examination Methods and EDX Analysis to Study the Archaeological Vitreous Enamels

Details

Type

Article

Created At

22 Jan 2023