Beta
265007

Regioselective synthesis of N-alkylated 4,6-diaryl-2-oxonicotinonitrile

Article

Last updated: 22 Jan 2023

Subjects

-

Tags

Basic and applied research of Chemistry,

Abstract

In the present work 4,6-diaryl-2-oxonicotinonitrile 1 reacts with serious of alkylating agents (ethyl bromoacetate, allyl bromide, propargyl bromide, chloroacetonitrile, chloroacetone, chloroacetic acid, epichlorohydrine, benzyl chloride, 1,3-dichloro isopropanol, 1,2-dichloroethane and 1,3-dibromopropane) by using K2CO3- NPs to form N-alkylated nicotinonitrile derivatives 2a-k. Also, the compounds 2j and 2k were reacted with another molecule of 2-oxonicotinonitrile 1 in the presence of K2CO3-NPs to afford the desired bis-pyridine ethane 4 and bi-pyridine propane 5, respectivelyIn the present work 4,6-diaryl-2-oxonicotinonitrile 1 reacts with serious of alkylating agents (ethyl bromoacetate, allyl bromide, propargyl bromide, chloroacetonitrile, chloroacetone, chloroacetic acid, epichlorohydrine, benzyl chloride, 1,3-dichloro isopropanol, 1,2-dichloroethane and 1,3-dibromopropane) by using K2CO3- NPs to form N-alkylated nicotinonitrile derivatives 2a-k. Also, the compounds 2j and 2k were reacted with another molecule of 2-oxonicotinonitrile 1 in the presence of K2CO3-NPs to afford the desired bis-pyridine ethane 4 and bi-pyridine propane 5, respectively.In the present work 4,6-diaryl-2-oxonicotinonitrile 1 reacts with serious of alkylating agents (ethyl bromoacetate, allyl bromide, propargyl bromide, chloroacetonitrile, chloroacetone, chloroacetic acid, epichlorohydrine, benzyl chloride, 1,3-dichloro isopropanol, 1,2-dichloroethane and 1,3-dibromopropane) by using K2CO3- NPs to form N-alkylated nicotinonitrile derivatives 2a-k. Also, the compounds 2j and 2k were reacted with another molecule of 2-oxonicotinonitrile 1 in the presence of K2CO3-NPs to afford the desired bis-pyridine ethane 4 and bi-pyridine propane 5, respectively.

DOI

10.21608/bfszu.2022.139178.1140

Keywords

K2CO3 Nano-catalyst, N-alkylation, 2-Oxonicotinonitrile, bis compounds

Authors

First Name

Hassan

Last Name

El-Sayed

MiddleName

A

Affiliation

Department of Chemistry, Faculty of Science, Zagazig University,

Email

hasanneg@gmail.com

City

Zagazig

Orcid

-

First Name

Sammar

Last Name

Mohamed

MiddleName

ع

Affiliation

الزقازيق

Email

chemistmarmar@gmail.com

City

الشرقية

Orcid

0000-0003-1209-2339

First Name

Ahmed

Last Name

Moustafa

MiddleName

H.

Affiliation

Department of Chemistry, Faculty of Science, Zagazig University, Zagazig, Egypt.

Email

ah_hu_mostafa@yahoo.com

City

Zagazig

Orcid

-

First Name

Aya

Last Name

Aymn

MiddleName

A

Affiliation

Department of Chemistry, Faculty of Science, Zagazig University,

Email

ayaamann@zu.ddu.eg

City

Zagazig

Orcid

-

Volume

2022

Article Issue

3

Related Issue

35750

Issue Date

2022-10-01

Receive Date

2022-05-17

Publish Date

2022-10-01

Page Start

59

Page End

68

Print ISSN

1110-1555

Link

https://bfszu.journals.ekb.eg/article_265007.html

Detail API

https://bfszu.journals.ekb.eg/service?article_code=265007

Order

6

Type

Original Article

Type Code

838

Publication Type

Journal

Publication Title

Bulletin of Faculty of Science, Zagazig University

Publication Link

https://bfszu.journals.ekb.eg/

MainTitle

-

Details

Type

Article

Created At

22 Jan 2023