37366

APPLICATION OF HTPB RUBBER MODIFIER FOR HIGH TEMPERATURE EPOXY ADHESIVE FORMULATIONS.

Article

Last updated: 04 Jan 2025

Subjects

-

Tags

-

Abstract

ABSTRACT Epoxy resins are widely utilized as high performance thermosetting adhesives. Polyamide cured epoxies provide improved flexibility, moisture resistance, and adhesion. Moreover, Versamid could provide lower viscosity, better compatibility, and better cure profiles under adverse conditions. Thus, the use of polyamide (Versamid 125) as a curing agent and HTPB as an elastomeric rubbery modifier give this study an importance in formulating adhesives to be used in high temperature applications. A systematic study has been conducted to investigate the modification of DGEBA-based epoxy systems by the incorporation of hydroxyl-terminated polybutadiene (HTPB) as an elastomeric rubbery modifier in different proportions (0.75, 1.5, 2.5, 5, and 10% by weight) into an epoxy resin. Mechanical mixing process, accompanied with vacuum to get rid of cavitations, was employed to disperse the particles homogeneously into the resin system. Thermal and mechanical properties of the composite and the neat resin were measured with DSC, Zwick universal test machine, and Zwick durometer hardness tester. The composite shows an improvement in stress, strain, shore D hardness, flexural and compressive values. Nearly 2.5% of HTPB was quite enough to obtain a compromise of the desired mechanical and thermal properties. The detected decrease in Tg as the rubber content increases means that this modifier can enhance plasticity of the matrix. Reduction in the cross-linking density of the thermoset because of the added modifier has been confirmed and explained.

DOI

10.21608/iccee.2010.37366

Keywords

Epoxy resins/ Adhesives/ Modifiers/ Thermal and mechanical properties / HTPB

Authors

First Name

Eyad

Last Name

Khalaf

MiddleName

S.

Affiliation

Egyptian Armed Forces.

Email

-

City

-

Orcid

-

First Name

Assem

Last Name

Hassan

MiddleName

H.

Affiliation

Egyptian Armed Forces.

Email

-

City

-

Orcid

-

First Name

Saeed

Last Name

Hassanein

MiddleName

M.

Affiliation

Egyptian Armed Forces.

Email

-

City

-

Orcid

-

First Name

Mostafa

Last Name

Hadhoud

MiddleName

K.

Affiliation

Egyptian Armed Forces.

Email

-

City

-

Orcid

-

Volume

5

Article Issue

5th International Conference on Chemical & Environmental Engineering

Related Issue

6024

Issue Date

2010-05-01

Receive Date

2019-06-26

Publish Date

2010-05-01

Page Start

1

Page End

11

Print ISSN

2636-4336

Online ISSN

2636-4344

Link

https://iccee.journals.ekb.eg/article_37366.html

Detail API

https://iccee.journals.ekb.eg/service?article_code=37366

Order

8

Type

Original Article

Type Code

832

Publication Type

Journal

Publication Title

The International Conference on Chemical and Environmental Engineering

Publication Link

https://iccee.journals.ekb.eg/

MainTitle

APPLICATION OF HTPB RUBBER MODIFIER FOR HIGH TEMPERATURE EPOXY ADHESIVE FORMULATIONS.

Details

Type

Article

Created At

22 Jan 2023