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35406

Studying the kinetics and mechanism of tartrazine removal by activated carbon under the influence of shaking speed using Diffusion-Binding model

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Last updated: 24 Dec 2024

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Abstract

Abstract The kinetic and mechanistic study of the removal rate of tartarzine by adsorption onto activated carbon under the influence of shaking speed is presented in this work. Diffusion binding model (DB-model) and pseudo second order model (PSO-model) were applied for suggesting the dependency of surface-reaction (solute or active site) and to give the main outputs; adsorption rate constants and capacities. According to error evaluation of both models, it was found that DB-model is more representative for tartarzine activated carbon adsorption system than PSO-model and it is suggested that surface-reaction kinetic is dependent on tartrazine concentration not on active sites of adsorbent. In addition, DB-model showed that adsorption rate constants and capacities increase with shaking speed which agrees with the fact of enhancing some diffusion steps because of shaking. DB-model, as a diffusion model as well, was applied to investigate diffusion mechanistic and it was concluded that for static condition (shaking speed = 0 rpm), adsorption passes two stages, the first is controlled by bulk-diffusion and film-diffusion and the second is controlled by intraparticle-diffusion. For shaking speeds 25 rpm and 50 rpm, bulk-diffusion and film-diffusion almost have no contribution in controlling overall rate and consequently intraparticle-diffusion is the controlling step. For shaking speeds from 75 to 125 rpm, intraparticle-diffusion is suggested to have strong contribution in controlling adsorption process.

DOI

10.21608/iccee.2014.35406

Keywords

Kinetics, Adsorption, Diffusion, DB-model, Tartrazine, Activated carbon

Authors

First Name

H.

Last Name

Albroomi

MiddleName

I.

Affiliation

Oman Armed Forces.

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City

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Orcid

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First Name

Ahmad

Last Name

Baraka

MiddleName

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Affiliation

Egyptian Armed Forces.

Email

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City

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Orcid

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First Name

M.

Last Name

Elsayed

MiddleName

A.

Affiliation

Egyptian Armed Forces.

Email

-

City

-

Orcid

-

First Name

M.

Last Name

Kassem

MiddleName

-

Affiliation

Egyptian Armed Forces.

Email

-

City

-

Orcid

-

Volume

7

Article Issue

7th International Conference on Chemical & Environmental Engineering

Related Issue

5842

Issue Date

2014-05-01

Receive Date

2019-06-18

Publish Date

2014-05-01

Page Start

1

Page End

8

Print ISSN

2636-4336

Online ISSN

2636-4344

Link

https://iccee.journals.ekb.eg/article_35406.html

Detail API

https://iccee.journals.ekb.eg/service?article_code=35406

Order

4

Type

Original Article

Type Code

832

Publication Type

Journal

Publication Title

The International Conference on Chemical and Environmental Engineering

Publication Link

https://iccee.journals.ekb.eg/

MainTitle

Studying the kinetics and mechanism of tartrazine removal by activated carbon under the influence of shaking speed using Diffusion-Binding model

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Article

Created At

22 Jan 2023