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35032

Radiation-induced graft copolymerization of vinyl monomer onto polyolefin polymeric substrate: preparation and characterization

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Last updated: 04 Jan 2025

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Abstract

Abstract
In this work, the synthesize of graft copolymers containing a functional group (carboxylic group) through mutual radiation grafting method for acrylic acid monomer onto high/ low density polyethylene substrate was investigated. The optimum conditions for radiation grafting were studied. In this regard, the effect of solvent type, monomer concentration, inhibitor concentration and irradiation dose on the grafting yield was determined.Some selected properties of the prepared graft copolymers were studied to illustrate the possibility of practical use in the industrial applications such as: water desalination, ion exchange, separation……etc. These properties were: water uptake, mechanical andelectrical propertiesandthe structure of the grafted membranes were investigated using Fourier transform infra-red (FTIR) analysis. The optimum conditions for mutual radiation grafting were achieved using acetone as asolvent,FeCl3as inhibitor with concentration 0.1 % (wt/wt),acrylic acid as monomer with concentration 30 % (wt/wt) and irradiation dose 20 kGy.

DOI

10.21608/iccee.2016.35032

Keywords

Gamma Irradiation, grafting, Polyolefin, Mechanical Properties

Authors

First Name

Hussein

Last Name

Oraby

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Affiliation

Department of Chemical Engineering, Military Technical Collage, Cairo, Egypt.

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First Name

Magdy

Last Name

Senna

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Affiliation

Radiation Chemistry Department, National Center for Radiation Research and Technology, P.O.Box 29 , Nasr City, Cairo, Egypt.

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Orcid

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First Name

Mohamed

Last Name

Elsayed

MiddleName

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Affiliation

Department of Chemical Engineering, Military Technical Collage, Cairo, Egypt.

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First Name

Mohamed

Last Name

Gobara

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-

Affiliation

Department of Chemical Engineering, Military Technical Collage, Cairo, Egypt.

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Volume

8

Article Issue

8th International Conference on Chemical & Environmental Engineering

Related Issue

5785

Issue Date

2016-04-01

Receive Date

2019-06-16

Publish Date

2016-04-01

Page Start

43

Page End

61

Print ISSN

2636-4336

Online ISSN

2636-4344

Link

https://iccee.journals.ekb.eg/article_35032.html

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https://iccee.journals.ekb.eg/service?article_code=35032

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3

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Original Article

Type Code

832

Publication Type

Journal

Publication Title

The International Conference on Chemical and Environmental Engineering

Publication Link

https://iccee.journals.ekb.eg/

MainTitle

Radiation-induced graft copolymerization of vinyl monomer onto polyolefin polymeric substrate: preparation and characterization

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Article

Created At

22 Jan 2023