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265514

SOLID-LIQUID PHASE EXTRACTION OF THORIUM (IV) FROM NITRATE LEACH LIQUORS USING AMINE FUNCTIONALIZED GLYCIDYL METHACRYLATE RESINS

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Last updated: 04 Jan 2025

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Abstract

Thorium adsorption from low concentration nitrate leach liquors was studied using glycidyl
methacrylate/divinyl benzene/amine polymers. RI and RII resins were prepared by the reaction of GMA/
DVB copolymers with ethylenediamine and diethylenediamine, respectively. The thermal stability of
the resins was studied thermogravimetrically. The prepared resins were applied for the adsorption of
thorium from synthetic and real samples. The results indicated that; the adsorption of Th(IV) increased as
the solution pH increased and the maximum metal adsorption was 50 and 64 mg/g for RI and RII,
respectively. Thorium (IV) adsorbed per mass unit of RI and RII resins increased from 50 to 64 and from
66 to 88 mg/g by increasing the temperature from 293o to 323o K respectively. The obtained results
indicated the applicability of RI and RII for Th(IV) adsorption. Finally, RI and RII resins were used
for the separation of Th(IV) from three granite samples leach liquors.

DOI

10.21608/nssj.2020.265514

Authors

First Name

MAHMOUD

Last Name

ABD EL-MAGIED

MiddleName

O.

Affiliation

Nuclear Materials Authority, Cairo , Egypt

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Orcid

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First Name

EL-SAYED

Last Name

MANAA

MiddleName

A.

Affiliation

Nuclear Materials Authority, Cairo , Egypt

Email

-

City

-

Orcid

-

First Name

MOHAMED

Last Name

KOURAIM

MiddleName

N.

Affiliation

Nuclear Materials Authority, Cairo , Egypt

Email

-

City

-

Orcid

-

First Name

MOHAMED

Last Name

YOUSSEF

MiddleName

A.

Affiliation

Nuclear Materials Authority, Cairo , Egypt

Email

-

City

-

Orcid

-

First Name

EKRAMY

Last Name

EL-DESOUKY

MiddleName

M.

Affiliation

Nuclear Materials Authority, Cairo , Egypt

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-

City

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-

Volume

9

Article Issue

1

Related Issue

37212

Issue Date

2020-04-01

Receive Date

2022-10-15

Publish Date

2020-04-01

Page Start

187

Page End

196

Print ISSN

2314-5609

Link

https://nssj.journals.ekb.eg/article_265514.html

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https://nssj.journals.ekb.eg/service?article_code=265514

Order

265,514

Type

Original Article

Type Code

798

Publication Type

Journal

Publication Title

Nuclear Sciences Scientific Journal

Publication Link

https://nssj.journals.ekb.eg/

MainTitle

SOLID-LIQUID PHASE EXTRACTION OF THORIUM (IV) FROM NITRATE LEACH LIQUORS USING AMINE FUNCTIONALIZED GLYCIDYL METHACRYLATE RESINS

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Article

Created At

22 Jan 2023