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25109

CONVERTING POLY(ETHYLENE TEREPHTHALATE) WASTE TO CURABLE RESINS

Article

Last updated: 04 Jan 2025

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Abstract

Different glycolyzed oligomers were prepared by depolymerization of poly(ethylene terephthalate), PET, waste in presence of manganese acetate catalyst. Diethylene glycol (DG), triethylene glycol (TG), propylene glycol (PG) and mixtures of DG/TG and DG/PG (50/50 wt%) were used for glycolysis. The weight ratio of PET to the glycol system was 1 : 0.65. The hydroxyl value of the glycolyzed products before and after removing the free glycol were determined. The amount of free glycol in each case was analyzed. These glycolyzed products were reacted with maleic anhydride, (MA) to prepare a series of unsaturated polyesters (UP) having different molecular weights. These polyesters were dissolved in styrene monomer and their curing behavior was investigated and compared with the curing behavior of UP made from virgin materials. The effect of accelerator and initiator concentrations on the curing characteristics of the recycled resins was studied. The mechanical properties and the hardness of the cured resins were measured and correlated to their molecular structure. The synthesized UP are intended to be used for repairing and maintaining the damaged runways and workshops of military airports.

DOI

10.21608/asat.1999.25109

Keywords

Unsaturated polyester, propylene glycol, Diethylene glycol, Triethylene glycol, poly(ethylene terephthalate), styrene, Curing, Glycolysis, recycling

Authors

First Name

Abdel-Azim

Last Name

Abdel-Azim

MiddleName

A.

Affiliation

Egyptian Petroleum Research Institute.

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City

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Orcid

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First Name

Guda

Last Name

R.

MiddleName

S.

Affiliation

Military Technical College, Kobry EI-Kobba, Cairo, Egypt.

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Volume

8

Article Issue

ASAT Conference, 4-6 May 1999

Related Issue

4551

Issue Date

1999-05-01

Receive Date

2019-01-17

Publish Date

1999-05-01

Page Start

1

Page End

13

Print ISSN

2090-0678

Online ISSN

2636-364X

Link

https://asat.journals.ekb.eg/article_25109.html

Detail API

https://asat.journals.ekb.eg/service?article_code=25109

Order

46

Type

Original Article

Type Code

737

Publication Type

Journal

Publication Title

International Conference on Aerospace Sciences and Aviation Technology

Publication Link

https://asat.journals.ekb.eg/

MainTitle

CONVERTING POLY(ETHYLENE TEREPHTHALATE) WASTE TO CURABLE RESINS

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Article

Created At

22 Jan 2023