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23390

Adsorption Nature of Tartrazine Dye onto Synthesized Melamine-Formaldehyde-Tartaric Acid (MF-T) Resin (Kinetic, Isotherm and Thermodynamic Studies)

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Last updated: 04 Jan 2025

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Abstract

The Melamine-Formaldehyde-Tartaric acid (MF-T) porous polymeric resin was synthesized in this work and examined as adsorbent for organic pollutants. Adsorption rate and isotherm of tartarzine, as an organic pollutant, onto MF-T from a synthetic wastewater was studied applying batch method. Initial concentration, contact time and temperature were considered as the variables of the adsorption experiments. Linear forms of pseudo-first and pseudo-second order kinetic models were applied using experimental adsorption-rate data. More than 60% of tartrazine was removed in the first 10 minutes and pseudo second-order model was found to well represent the adsorption kinetics with average capacity of about 23 mg/g over the studied temperature span. Linear forms of Langmuir and Freundlich isotherm models were applied using experimental adsorption-equilibrium data. In general, Freundlich model is selected to represent the adsorption isotherm. It was found that adsorption mechanism is temperature sensitive but retain spontaneous over the studied temperature span. Thermodynamic study revealed that physical mechanism contributes at low temperature range (15-30oC) and a dual mechanism of physical and chemical natures is postulated at the higher temperature range (30-45oC). The chemical part is suggested to be endothermic amide bonding of tartrazine with resin reactive functional groups.

DOI

10.21608/asat.2011.23390

Keywords

Polymeric resin, chemical, physical, Adsorption, Wastewater, dyes

Authors

First Name

Ahmad

Last Name

Baraka

MiddleName

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Affiliation

Egyptian Armed Forces, Egypt.

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Volume

14

Article Issue

AEROSPACE SCIENCES & AVIATION TECHNOLOGY, ASAT - 14 – May 24 - 26, 2011

Related Issue

4330

Issue Date

2011-05-01

Receive Date

2019-01-02

Publish Date

2011-05-01

Page Start

1

Page End

15

Print ISSN

2090-0678

Online ISSN

2636-364X

Link

https://asat.journals.ekb.eg/article_23390.html

Detail API

https://asat.journals.ekb.eg/service?article_code=23390

Order

76

Type

Original Article

Type Code

737

Publication Type

Journal

Publication Title

International Conference on Aerospace Sciences and Aviation Technology

Publication Link

https://asat.journals.ekb.eg/

MainTitle

Adsorption Nature of Tartrazine Dye onto Synthesized Melamine-Formaldehyde-Tartaric Acid (MF-T) Resin (Kinetic, Isotherm and Thermodynamic Studies)

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Article

Created At

22 Jan 2023